Effect of H2S on the S-PAH formation during ethylene pyrolysis

Adánez-Rubio, I. ; Millera, Á. (Universidad de Zaragoza) ; Bilbao, R. (Universidad de Zaragoza) ; Alzueta, M.U. (Universidad de Zaragoza)

Resumen: The effect of the H2S presence on the formation of six different sulphurated polycyclic hydrocarbons (S-PAH), during the pyrolysis of ethylene-H2S mixtures, has been studied in a tubular flow reactor installation. Experiments with different inlet H2S concentrations (0.3, 0.5 and 1%) and temperatures of reaction (between 1075 and 1475 K) have been carried out. The 16 compounds that the Environmental Protection Agency (EPA) has stated as EPA-PAH priority pollutants were also analysed. EPA-PAH compounds were the majority of quantified PAH, and also S-PAH were found and quantified. For temperatures studied, the S-PAH/EPA-PAH ratio values showed a maximum value at 1075 K and a minimum value at 1175 K. With respect to the effect of the inlet concentration of H2S, the S-PAH/EPA-PAH ratio values increased with the increase of the H2S concentration.

Idioma: Inglés

DOI: 10.1016/j.fuel.2020.118033

Año: 2020

Publicado en: Fuel 276 (2020), 118033 [7 pp.]
ISSN: 0016-2361

Factor impacto JCR: 6.609 (2020)

Categ. JCR: ENGINEERING, CHEMICAL rank: 20 / 143 = 0.14 (2020) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 27 / 114 = 0.237 (2020) - Q1 - T1

Factor impacto SCIMAGO: 1.56 - Chemical Engineering (miscellaneous) (Q1) - Organic Chemistry (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R
Financiación: info:eu-repo/grantAgreement/ES/MCIU/RTI2018-098856-B-100
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-65226-R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/FJCI-2015-23862

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)