Interaction of NH3 and NO under combustion conditions. Experimental flow reactor study and kinetic modeling simulation

Alzueta, M.U. (Universidad de Zaragoza) ; Ara, L. ; Mercader, V.D. (Universidad de Zaragoza) ; Delogu, M. ; Bilbao, R. (Universidad de Zaragoza)

Resumen: The interaction between ammonia and NO under combustion conditions is analyzed in the present work, from both experimental and kinetic modelling points of view. An experimental systematic study of the influence of the main variables for the NH3sbnd]NO interaction is made using a laboratory tubular flow reactor installation. Experiments are performed at atmospheric pressure and variables analyzed include: temperature in the 700–1500 K range, air stoichiometry, from pyrolysis to very oxidizing conditions, and the NH3/NO ratio, in the 0.7–3.5 range. Nitrogen and argon have been used as diluent gas. A literature reaction mechanism has been used to simulate the present experimental results and discuss the main findings. Reaction path analysis has allowed the identification of the reaction routes under the studied conditions. The simulations reflect the main experimental trends observed. Main results show that NO reduction by NH3 occurs at any conditions studied, but is more intense under oxygen excess conditions. Interactions of NH3 and NO proceeds in a molar basis with optimum conversions of NO of up to almost 100%. © 2021

Idioma: Inglés

DOI: 10.1016/j.combustflame.2021.111691

Año: 2022

Publicado en: Combustion and Flame 235 (2022), 111691 [9 pp.]
ISSN: 0010-2180

Factor impacto JCR: 4.4 (2022)

Categ. JCR: ENGINEERING, MECHANICAL rank: 29 / 136 = 0.213 (2022) - Q1 - T1
Categ. JCR: THERMODYNAMICS rank: 13 / 63 = 0.206 (2022) - Q1 - T1
Categ. JCR: ENGINEERING, MULTIDISCIPLINARY rank: 23 / 90 = 0.256 (2022) - Q2 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 43 / 141 = 0.305 (2022) - Q2 - T1
Categ. JCR: ENERGY & FUELS rank: 62 / 119 = 0.521 (2022) - Q3 - T2

Factor impacto CITESCORE: 8.4 - Physics and Astronomy (Q1) - Chemistry (Q1) - Chemical Engineering (Q1) - Energy (Q1)

Factor impacto SCIMAGO: 0.878 - Chemical Engineering (miscellaneous) (Q1) - Chemistry (miscellaneous) (Q1) - Physics and Astronomy (miscellaneous) (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q2)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R
Financiación: info:eu-repo/grantAgreement/ES/MCIU-FEDER/RTI2018-098856-B-100

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
Área (Departamento): Área Tecnologi. Medio Ambiente (Dpto. Ing.Quím.Tecnol.Med.Amb.)