Stellated cuboctahedron of Fe III

Wilson, Lucinda R. B. ; Canaj, Angelos B. ; Cutler, Daniel J. ; McCormick McPherson, Laura J. ; Coles, Simon J. ; Nojiri, Hiroyuki ; Evangelisti, Marco ; Schnack, Jürgen ; Dalgarno, Scott J. ; Brechin, Euan K.

Resumen: The solvothermal reaction of FeCl2 ⋅ 4H2O and H4TBC[4] in a basic dmf/EtOH solution affords an [FeIII18] Keplerate conforming to a stellated cuboctahedron. Magnetic and heat capacity measurements reveal spin frustration effects arising from the high symmetry. A crossover between inverse and direct magnetocaloric effects is observed at ~10 K for applied-field changes lower than 3 T.

Idioma: Inglés

DOI: 10.1002/anie.202405666

Año: 2024

Publicado en: Angewandte Chemie (International ed.) 63, 37 (2024), e202405666 [6 pp.]
ISSN: 1433-7851

Factor impacto JCR: 17.0 (2024)

Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 15 / 239 = 0.063 (2024) - Q1 - T1

Factor impacto CITESCORE: 27.6 - Catalysis (Q1) - Chemistry (all) (Q1)

Factor impacto SCIMAGO: 5.55 - Chemistry (miscellaneous) (Q1) - Catalysis (Q1)

Financiación: info:eu-repo/grantAgreement/ES/MICINN/PID2021-124734OB-C21

Tipo y forma: Comunicación congreso (Versión definitiva)