000056141 001__ 56141
000056141 005__ 20210121114526.0
000056141 0247_ $$2doi$$a10.1039/c5nr01031d
000056141 0248_ $$2sideral$$a89488
000056141 037__ $$aART-2015-89488
000056141 041__ $$aeng
000056141 100__ $$aMalumbres, A.
000056141 245__ $$aFacile production of stable silicon nanoparticles: laser chemistry coupled to in situ stabilization via room temperature hydrosilylation
000056141 260__ $$c2015
000056141 5060_ $$aAccess copy available to the general public$$fUnrestricted
000056141 5203_ $$aStable, alkyl-terminated, light-emitting silicon nanoparticles have been synthesized in a continuous process by laser pyrolysis of a liquid trialkyl-silane precursor selected as a safer alternative to gas silane (SiH4). Stabilization was achieved by in situ reaction using a liquid collection system instead of the usual solid state filtration. The alkene contained in the collection liquid (1-dodecene) reacted with the newly formed silicon nanoparticles in an unusual room-temperature hydrosilylation process. It was achieved by the presence of fluoride species, also produced during laser pyrolysis from the decomposition of sulfur hexafluoride (SF6) selected as a laser sensitizer. This process directly rendered alkyl-passivated silicon nanoparticles with consistent morphology and size (<3 nm), avoiding the use of costly post-synthetic treatments.
000056141 536__ $$9info:eu-repo/grantAgreement/EC/FP7/294094/EU/Synthesis and characterization of NANOstructured materials with LumInescent properties for diaGnostic and tHerapeuTic applications/NANOLIGHT
000056141 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000056141 590__ $$a7.76$$b2015
000056141 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b23 / 271 = 0.085$$c2015$$dQ1$$eT1
000056141 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b12 / 83 = 0.145$$c2015$$dQ1$$eT1
000056141 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b18 / 163 = 0.11$$c2015$$dQ1$$eT1
000056141 591__ $$aPHYSICS, APPLIED$$b12 / 145 = 0.083$$c2015$$dQ1$$eT1
000056141 592__ $$a2.77$$b2015
000056141 593__ $$aNanoscience and Nanotechnology$$c2015$$dQ1
000056141 593__ $$aMaterials Science (miscellaneous)$$c2015$$dQ1
000056141 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000056141 700__ $$0(orcid)0000-0001-7872-6301$$aMartinez, G.$$uUniversidad de Zaragoza
000056141 700__ $$0(orcid)0000-0002-4546-4111$$aHueso, J.L.
000056141 700__ $$0(orcid)0000-0001-7528-6582$$aGracia, J.
000056141 700__ $$aMallada, R.
000056141 700__ $$aIbarra, A.
000056141 700__ $$aSantamaria, J.
000056141 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000056141 773__ $$g7 (2015), 8566-8573$$pNanoscale$$tNanoscale$$x2040-3364
000056141 8564_ $$s2294640$$uhttps://zaguan.unizar.es/record/56141/files/texto_completo.pdf$$yVersión publicada
000056141 8564_ $$s114127$$uhttps://zaguan.unizar.es/record/56141/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000056141 909CO $$ooai:zaguan.unizar.es:56141$$particulos$$pdriver
000056141 951__ $$a2021-01-21-11:06:32
000056141 980__ $$aARTICLE