000056317 001__ 56317
000056317 005__ 20200221144339.0
000056317 0247_ $$2doi$$a10.1038/nchem.2374
000056317 0248_ $$2sideral$$a93083
000056317 037__ $$aART-2016-93083
000056317 041__ $$aeng
000056317 100__ $$aMazur, M.
000056317 245__ $$aSynthesis of ‘unfeasible’ zeolites
000056317 260__ $$c2016
000056317 5060_ $$aAccess copy available to the general public$$fUnrestricted
000056317 5203_ $$aZeolites are porous aluminosilicate materials that have found applications in many different technologies. However, although simulations suggest that there are millions of possible zeolite topologies, only a little over 200 zeolite frameworks of all compositions are currently known, of which about 50 are pure silica materials. This is known as the zeolite conundrum—why have so few of all the possible structures been made? Several criteria have been formulated to explain why most zeolites are unfeasible synthesis targets. Here we demonstrate the synthesis of two such unfeasible’ zeolites, IPC-9 and IPC-10, through the assembly–disassembly–organization–reassembly mechanism. These new high-silica zeolites have rare characteristics, such as windows that comprise odd-membered rings. Their synthesis opens up the possibility of preparing other zeolites that have not been accessible by traditional solvothermal synthetic methods. We envisage that these findings may lead to a step change in the number and types of zeolites available for future applications.
000056317 536__ $$9info:eu-repo/grantAgreement/EC/FP7/312483/EU/Enabling Science and Technology through European Electron Microscopy/ESTEEM 2
000056317 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000056317 590__ $$a25.87$$b2016
000056317 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b4 / 166 = 0.024$$c2016$$dQ1$$eT1
000056317 592__ $$a12.648$$b2016
000056317 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000056317 593__ $$aChemical Engineering (miscellaneous)$$c2016$$dQ1
000056317 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000056317 700__ $$aWheatley, P. S.
000056317 700__ $$0(orcid)0000-0001-7702-9619$$aNavarro, M.
000056317 700__ $$aRoth, W. J.
000056317 700__ $$aPoložij, M.
000056317 700__ $$0(orcid)0000-0002-5229-2717$$aMayoral, A.
000056317 700__ $$aEliášová, P.
000056317 700__ $$aNachtigall, P.
000056317 700__ $$aCejka, J.
000056317 700__ $$aMorris, R. E.
000056317 773__ $$g8 (2016), 58–62$$pNature Chemistry$$tNature Chemistry$$x1755-4330
000056317 8564_ $$s829354$$uhttp://zaguan.unizar.es/record/56317/files/texto_completo.pdf$$yPostprint
000056317 8564_ $$s81217$$uhttp://zaguan.unizar.es/record/56317/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000056317 909CO $$ooai:zaguan.unizar.es:56317$$particulos$$pdriver
000056317 951__ $$a2020-02-21-13:49:01
000056317 980__ $$aARTICLE