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000056360 0247_ $$2doi$$a10.1016/j.jct.2015.09.012
000056360 0248_ $$2sideral$$a92301
000056360 037__ $$aART-2016-92301
000056360 041__ $$aeng
000056360 100__ $$0(orcid)0000-0001-6182-2196$$aMartínez-López, J.F.$$uUniversidad de Zaragoza
000056360 245__ $$aMolar heat capacities of the mixture {1, 8-cineole + ethanol} at several temperatures and atmospheric pressure
000056360 260__ $$c2016
000056360 5060_ $$aAccess copy available to the general public$$fUnrestricted
000056360 5203_ $$aMolar heat capacities at atmospheric pressure have been determined every 5 K for the mixture {1, 8-cineole (1) + ethanol (2)} in the temperature interval (304.7 to 324.5) K and the whole composition range with a Calvet type calorimeter Setaram C80. From the molar heat capacities, excess molar heat capacities have been calculated, their values being positive and increasing as the temperature rises. The solvation model COSMO-RS has been applied to predict the excess molar heat capacities. The model overestimates the values of the excess heat capacities but predicts well the trend of variation of the excess molar heat capacity with the temperature.
000056360 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2012-38219-C03-02
000056360 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000056360 590__ $$a2.726$$b2016
000056360 591__ $$aTHERMODYNAMICS$$b13 / 58 = 0.224$$c2016$$dQ1$$eT1
000056360 591__ $$aCHEMISTRY, PHYSICAL$$b64 / 145 = 0.441$$c2016$$dQ2$$eT2
000056360 592__ $$a0.971$$b2016
000056360 593__ $$aAtomic and Molecular Physics, and Optics$$c2016$$dQ1
000056360 593__ $$aPhysical and Theoretical Chemistry$$c2016$$dQ1
000056360 593__ $$aMaterials Science (miscellaneous)$$c2016$$dQ1
000056360 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000056360 700__ $$aSchneider, S.
000056360 700__ $$aSalavera, D.
000056360 700__ $$0(orcid)0000-0001-9379-8047$$aMainar, A.M.$$uUniversidad de Zaragoza
000056360 700__ $$0(orcid)0000-0001-7569-5036$$aUrieta, J.S.$$uUniversidad de Zaragoza
000056360 700__ $$0(orcid)0000-0002-0661-9889$$aPardo, J.I.$$uUniversidad de Zaragoza
000056360 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000056360 773__ $$g92 (2016), 146-151$$pJ. Chem. Thermodyn.$$tJournal of Chemical Thermodynamics$$x0021-9614
000056360 8564_ $$s378437$$uhttps://zaguan.unizar.es/record/56360/files/texto_completo.pdf$$yPostprint
000056360 8564_ $$s62912$$uhttps://zaguan.unizar.es/record/56360/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000056360 909CO $$ooai:zaguan.unizar.es:56360$$particulos$$pdriver
000056360 951__ $$a2020-02-21-13:02:23
000056360 980__ $$aARTICLE