Tunable crossover between one- and three-dimensional magnetic dynamics in C oII single-chain magnets organized by halogen bonding

Amjad, A. ; Clemente-Juan, J. ; Coronado, E. ; Luis, F. (Universidad de Zaragoza) ; Evangelisti, M. (Universidad de Zaragoza) ; Minguez Espallargas, G. ; Del Barco, E.

Resumen: Low-temperature magnetometry, ac susceptibility, and calorimetry have been employed to study Co-based single-chain magnets (SCMs) organized through halogen bonding. Magnetic hysteresis and maxima in the dc and ac susceptibilities, respectively, confirm the SCM behavior of the system. Several characteristic magnetic relaxation regimes are observed at different temperatures, which can be associated with both intra- and interchain exchange interactions. Remarkably, tweaking the rate at which an external magnetic field is swept along the axis of the chains enables a controlled transition between the one- and three-dimensional dynamics. Experiments on an isostructural Co-based SCM system crystallized with different halogens do not show three-dimensional dynamics, illustrating the importance of halogen bonding on the control of interchain interactions.

Idioma: Inglés

DOI: 10.1103/PhysRevB.93.224418

Año: 2016

Publicado en: Physical Review B. Condensed Matter and Materials Physics 93, 22 (2016), 224418 [9 p.]
ISSN: 1098-0121

Factor impacto JCR: 3.836 (2016)

Categ. JCR: PHYSICS, CONDENSED MATTER rank: 18 / 67 = 0.269 (2016) - Q2 - T1

Factor impacto SCIMAGO: 2.339 - Electronic, Optical and Magnetic Materials (Q1) - Condensed Matter Physics (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E98-MOLCHIP
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-29509-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-52758-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2014-52919-REDC
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MAT2014-56143-R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/MDM-2015-0538
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/MAT2015-68204-R

Tipo y forma: Artículo (Versión definitiva)

Área (Departamento): Área Física Materia Condensada (Dpto. Física Materia Condensa.)