Financiación H2020 / H2020 Funds
Resumen: A bimetallic [Ir3+]2 complex was synthesized based on a bridging 1,2,3-triazole ligand that coordinates to one Cp*Ir unit as N,N-bidentate chelate, and to the other as a C,C-bidentate ligand. When compared to monometallic homologues, the bimetallic complex shows greatly enhanced product selectivity for the acceptorless dehydrogenation of alcohols; spectroscopic and electrochemical analysis suggest significant alteration of the metal properties in the bimetallic system compared to the monometallic species, which offers a rationale for the observed high selectivity.
Idioma: Inglés
DOI: 10.1039/c6cc00267f
Año: 2016
Publicado en: CHEMICAL COMMUNICATIONS 52 (2016), 3344-3347
ISSN: 1359-7345

Factor impacto JCR: 6.319 (2016)
Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 23 / 166 = 0.139 (2016) - Q1 - T1
Factor impacto SCIMAGO: 2.537 - Catalysis (Q1) - Ceramics and Composites (Q1) - Chemistry (miscellaneous) (Q1) - Surfaces, Coatings and Films (Q1) - Materials Chemistry (Q1) - Metals and Alloys (Q1) - Electronic, Optical and Magnetic Materials (Q1)

Financiación: info:eu-repo/grantAgreement/EC/H2020/660929/EU/CoopClickCat/CoopClickCat
Financiación: info:eu-repo/grantAgreement/EC/H2020/660929/EU/CoopClickCat/CoopClickCat
Tipo y forma: Congress (Published version)

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 Record created 2016-12-19, last modified 2020-02-21


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