000060603 001__ 60603
000060603 005__ 20200221144127.0
000060603 0247_ $$2doi$$a10.1016/j.jcat.2015.11.016
000060603 0248_ $$2sideral$$a93220
000060603 037__ $$aART-2016-93220
000060603 041__ $$aeng
000060603 100__ $$aMurillo, B.
000060603 245__ $$aChemocatalysis of sugars to produce lactic acid derivatives on zeolitic imidazolate frameworks
000060603 260__ $$c2016
000060603 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060603 5203_ $$aSeveral research studies related to biorefining have focused on developing routes for biomass conversion into biomaterials or platform molecules. In this work, the zeolitic imidazolate frameworks (ZIFs) ZIF-8 and ZIF-67 have been tested as catalysts in the conversion of sugars (sucrose, glucose and fructose) into methyl lactate. ZIF-8 and ZIF-67 have the same sodalite type zeolite structure but behaved differently in the sugar conversion in methanol due to the respective presence of Zn and Co in their structures. ZIF-8 has been found to be the most active for the conversion of sugars into methyl lactate (yield 42%) and was reused in four catalytic cycles. The chemical and physical effects caused by these cycles on the catalysts have been studied by several techniques (X-ray diffraction, thermogravimetric analyses, infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electronic microscopy and nitrogen adsorption).
000060603 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R$$9info:eu-repo/grantAgreement/ES/DGA/T05
000060603 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000060603 590__ $$a6.844$$b2016
000060603 591__ $$aENGINEERING, CHEMICAL$$b5 / 135 = 0.037$$c2016$$dQ1$$eT1
000060603 591__ $$aCHEMISTRY, PHYSICAL$$b20 / 145 = 0.138$$c2016$$dQ1$$eT1
000060603 592__ $$a2.451$$b2016
000060603 593__ $$aPhysical and Theoretical Chemistry$$c2016$$dQ1
000060603 593__ $$aCatalysis$$c2016$$dQ1
000060603 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000060603 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, B.
000060603 700__ $$0(orcid)0000-0003-0297-3503$$aDe La Iglesia, O.
000060603 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, C.$$uUniversidad de Zaragoza
000060603 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000060603 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000060603 773__ $$g334 (2016), 60-67$$pJ. catal.$$tJournal of Catalysis$$x0021-9517
000060603 8564_ $$s1061262$$uhttp://zaguan.unizar.es/record/60603/files/texto_completo.pdf$$yPostprint
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000060603 909CO $$ooai:zaguan.unizar.es:60603$$particulos$$pdriver
000060603 951__ $$a2020-02-21-13:03:57
000060603 980__ $$aARTICLE