000060604 001__ 60604
000060604 005__ 20171002111020.0
000060604 0247_ $$2doi$$a10.1039/c5ra20172a
000060604 0248_ $$2sideral$$a93260
000060604 037__ $$aART-2015-93260
000060604 041__ $$aeng
000060604 100__ $$0(orcid)0000-0003-1273-2690$$aSorribas, S.
000060604 245__ $$aInsight into ETS-10 synthesis for the preparation of mixed matrix membranes for CO2/CH4 gas separation
000060604 260__ $$c2015
000060604 5060_ $$aAccess copy available to the general public$$fUnrestricted
000060604 5203_ $$aAn in-depth study into the synthesis of the titanosilicate ETS-10 has been carried out to obtain crystals with different particle sizes, roughness and porosity. The effect of these parameters on the CO2/CH4 gas separation performance using mixed matrix membranes (MMMs) has been studied. MMMs based on ETS-10 polycrystalline particles of 1-2 µm in size with high surface roughness and porosity gave rise to a good filler dispersion and filler-polymer interaction. The addition of 10 wt% ETS-10 polycrystalline particles into the polysulfone matrix increased the CO2 permeability from 6.1 to 7.8 Barrer and the CO2/CH4 selectivity from 31 to 38. When using the polyimide 6FDA-6FpDA, a glassy polymer with high gas permeability, the addition of 10 wt% ETS-10 polycrystalline particles increased the CO2 permeability from 96 to 125 Barrer, with a decrease in CO2/CH4 selectivity from 56 to 51.
000060604 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-45071-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2013-40566-R$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2011-25513$$9info:eu-repo/grantAgreement/ES/DGA/T05
000060604 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000060604 590__ $$a3.289$$b2015
000060604 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b48 / 162 = 0.296$$c2015$$dQ2$$eT1
000060604 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000060604 700__ $$aComesaña-Gándara, B.
000060604 700__ $$aLozano, A.E.
000060604 700__ $$0(orcid)0000-0002-9934-1707$$aZornoza, B.
000060604 700__ $$0(orcid)0000-0002-4954-1188$$aTéllez, C.$$uUniversidad de Zaragoza
000060604 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000060604 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDepartamento de Ingeniería Química y Tecnologías del Medio Ambiente$$cIngeniería Química
000060604 773__ $$g5, 124 (2015), 102392-102398$$pRSC ADVANCES$$tRSC ADVANCES$$x2046-2069
000060604 8564_ $$s715144$$uhttp://zaguan.unizar.es/record/60604/files/texto_completo.pdf$$yVersión publicada
000060604 8564_ $$s118340$$uhttp://zaguan.unizar.es/record/60604/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000060604 909CO $$ooai:zaguan.unizar.es:60604$$particulos$$pdriver
000060604 951__ $$a2017-10-02-10:49:41
000060604 980__ $$aARTICLE