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> Double hydrophosphination of alkynes promoted by rhodium: The key role of an N-heterocyclic carbene ligand
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Double hydrophosphination of alkynes promoted by rhodium: The key role of an N-heterocyclic carbene ligand
Di Giuseppe, Andrea
(Universidad de Zaragoza)
;
De Luca, Roberto
;
Castarlenas, Ricardo
(Universidad de Zaragoza)
;
Pérez-Torrente, Jesús J..
(Universidad de Zaragoza)
;
Crucianelli, Marcello
;
Oro, Luis A.
(Universidad de Zaragoza)
Resumen:
The regioselective double hydrophosphination of alkynes mediated by rhodium catalysts is presented. The distinctive stereoelectronic properties of the NHC ligand prevent the catalyst deactivation by diphosphine coordination thereby allowing for the closing of a productive catalytic cycle.
Idioma:
Inglés
DOI:
10.1039/c5cc09156j
Año:
2016
Publicado en:
CHEMICAL COMMUNICATIONS
52, 32 (2016), 5554-5557
ISSN:
1359-7345
Factor impacto JCR:
6.319 (2016)
Categ. JCR:
CHEMISTRY, MULTIDISCIPLINARY
rank: 23 / 166 = 0.139
(2016)
- Q1
- T1
Factor impacto SCIMAGO:
2.537 -
Catalysis
(Q1) -
Ceramics and Composites
(Q1) -
Chemistry (miscellaneous)
(Q1) -
Surfaces, Coatings and Films
(Q1) -
Materials Chemistry
(Q1) -
Metals and Alloys
(Q1) -
Electronic, Optical and Magnetic Materials
(Q1)
Financiación:
info:eu-repo/grantAgreement/ES/DGA/E07
Financiación:
info:eu-repo/grantAgreement/ES/MICINN-FEDER/CSD2009-00050
Financiación:
info:eu-repo/grantAgreement/ES/MINECO/CTQ2013-42532-P
Tipo y forma:
Congress (PostPrint)
Área (Departamento):
Área Química Inorgánica
(
Dpto. Química Inorgánica
)
All rights reserved by journal editor
Exportado de SIDERAL (2020-08-11-09:02:33)
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