Antioxidants for biodiesel: Additives prepared from extracted fractions of bio-oil
García Rodríguez, Manuel ; Botella Abad, Lucía ; Gil-Lalaguna, Noemí ; Arauzo Pérez, Jesús (Universidad de Zaragoza) ; Gonzalo Callejo, Aberto (Universidad de Zaragoza) ; Sánchez Cebrián, José Luis (Universidad de Zaragoza)
Resumen: Unlike petroleum diesel, the chemical structure of biodiesel makes it prone to oxidation during long-term storage, thus involving fuel quality deterioration. Therefore, the addition of antioxidants is usually required to meet the quality standards for biodiesel commercialization. Synthetic sterically-hindered phenols have been usually employed for this purpose as free radical scavenging antioxidants. However, naturally occurring phenolics are also available, for example, in the bio-oil produced in the pyrolysis of lignocellulosic biomass. In this work, the antioxidant potential of extracted fractions of lignocellulosic bio-oil has been evaluated. Different organic solvents were tested as extraction agents, acetate esters being the best ones for incorporating bio-oil antioxidant compounds into biodiesel. In the best case, the incorporation of a small concentration of bio-oil compounds (< 4 wt.%) led to an improvement of the biodiesel oxidation stability of 475% which, in our case, was enough to meet the European standard requirement.
Idioma: Inglés
DOI: 10.1016/j.fuproc.2016.10.001
Año: 2017
Publicado en: Fuel Processing Technology 156 (2017), 407-414
ISSN: 0378-3820
Factor impacto JCR: 3.956 (2017)
Categ. JCR: CHEMISTRY, APPLIED rank: 8 / 71 = 0.113 (2017) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 21 / 137 = 0.153 (2017) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 29 / 97 = 0.299 (2017) - Q2 - T1
Factor impacto SCIMAGO: 1.453 - Chemical Engineering (miscellaneous) (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/GPT
Financiación: info:eu-repo/grantAgreement/ES/MINECO/ENE2013-41523-R
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material.
Exportado de SIDERAL (2019-09-30-12:52:59)
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Idioma: Inglés
DOI: 10.1016/j.fuproc.2016.10.001
Año: 2017
Publicado en: Fuel Processing Technology 156 (2017), 407-414
ISSN: 0378-3820
Factor impacto JCR: 3.956 (2017)
Categ. JCR: CHEMISTRY, APPLIED rank: 8 / 71 = 0.113 (2017) - Q1 - T1
Categ. JCR: ENGINEERING, CHEMICAL rank: 21 / 137 = 0.153 (2017) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 29 / 97 = 0.299 (2017) - Q2 - T1
Factor impacto SCIMAGO: 1.453 - Chemical Engineering (miscellaneous) (Q1) - Fuel Technology (Q1) - Energy Engineering and Power Technology (Q1)
Financiación: info:eu-repo/grantAgreement/ES/DGA/GPT
Financiación: info:eu-repo/grantAgreement/ES/MINECO/ENE2013-41523-R
Tipo y forma: Article (PostPrint)
Área (Departamento): Área Ingeniería Química (Dpto. Ing.Quím.Tecnol.Med.Amb.)
You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use. You may not use the material for commercial purposes. If you remix, transform, or build upon the material, you may not distribute the modified material. Exportado de SIDERAL (2019-09-30-12:52:59)
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Record created 2017-11-29, last modified 2019-09-30