000070909 001__ 70909
000070909 005__ 20210416092954.0
000070909 0247_ $$2doi$$a10.1039/c6ra06835a
000070909 0248_ $$2sideral$$a106256
000070909 037__ $$aART-2016-106256
000070909 041__ $$aeng
000070909 100__ $$0(orcid)0000-0002-5826-7600$$aGracia, I.
000070909 245__ $$aFunctional organogelators formed by liquid-crystal carbazole-containing bis-MPA dendrimers
000070909 260__ $$c2016
000070909 5060_ $$aAccess copy available to the general public$$fUnrestricted
000070909 5203_ $$aNovel functional gelators with a dendritic structure based on flexible bis-MPA dendrons that combine mesogenic and carbazole moieties have been prepared. Both the precursory dendrons and the resulting codendrimers show rich supramolecular chemistry, exhibiting both liquid crystalline phases and gelling properties in several low-polarity organic solvents. The study of the self-assembly processes reveals that non-covalent weak interactions control the formation of the supramolecular gels. Due to the carbazole moieties, these gels show interesting electronic properties with an increased fluorescence emission arising from an aggregation-induced emission enhancement (AIEE) effect and electrochemical behaviour. Oxidative polymerisation has been proven to be effective for fixing the gel structure in thin layers of xerogels deposited on ITO electrodes.
000070909 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E04$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-70174-P
000070909 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000070909 590__ $$a3.108$$b2016
000070909 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b59 / 166 = 0.355$$c2016$$dQ2$$eT2
000070909 592__ $$a0.889$$b2016
000070909 593__ $$aChemistry (miscellaneous)$$c2016$$dQ1
000070909 593__ $$aChemical Engineering (miscellaneous)$$c2016$$dQ1
000070909 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000070909 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000070909 700__ $$0(orcid)0000-0001-5816-7960$$aBarbera, J.$$uUniversidad de Zaragoza
000070909 700__ $$0(orcid)0000-0002-3661-2485$$aOmenat, A.
000070909 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000070909 773__ $$g6, 46 (2016), 39734-39740$$pRSC ADVANCES$$tRSC Advances$$x2046-2069
000070909 8564_ $$s256663$$uhttps://zaguan.unizar.es/record/70909/files/texto_completo.pdf$$yVersión publicada
000070909 8564_ $$s120109$$uhttps://zaguan.unizar.es/record/70909/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000070909 909CO $$ooai:zaguan.unizar.es:70909$$particulos$$pdriver
000070909 951__ $$a2021-04-16-09:24:49
000070909 980__ $$aARTICLE