Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

Esteruelas, M.A. ; Fernández, I. ; García-Yebra, C. ; Martín, J. (Universidad de Zaragoza) ; Oñate, E.

Resumen: The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH 3 NHR 2 amine-borane, bear an Os-S-B three-membered ring, being a manifestation of the 4n + 2 Hückel aromaticity in which n = 0 and where the two p electrons of the ring are provided by the S atom.

Idioma: Inglés

DOI: 10.1021/acs.inorgchem.8b03366

Año: 2019

Publicado en: Inorganic Chemistry 58, 4 (2019), 2265-2269
ISSN: 0020-1669

Factor impacto JCR: 4.825 (2019)

Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 4 / 45 = 0.089 (2019) - Q1 - T1

Factor impacto SCIMAGO: 1.349 - Chemistry (miscellaneous) (Q1) - Physical and Theoretical Chemistry (Q1) - Inorganic Chemistry (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/E06-17R
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-78205-P
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-81797-REDC
Financiación: info:eu-repo/grantAgreement/ES/MINECO/CTQ2017-82935-P

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)