Rhodium-catalyzed formation of silylcarbamates from the reaction of secondary amines with CO2 and hydrosilanes

Guzmán, Jefferson (Universidad de Zaragoza) ; Torguet, Adrían ; García-Orduña, Pilar (Universidad de Zaragoza) ; Lahoz, Fernando J. (Universidad de Zaragoza) ; Oro, Luis A. (Universidad de Zaragoza) ; Fernández-Alvarez, Francisco J. (Universidad de Zaragoza)

Resumen: The reaction of (4-methyl-pyridine-2-iloxy)dimethylsilane (NSiMe–H, 1) with [RhCl(coe)2]2 gives the rhodium(III) complex [Rh(Cl)(¿2-NSiMe)2] (2), which reacts with a stoichiometric amount of AgCF3CO2 to afford [Rh(¿2-CF3CO2)(¿2-NSiMe)2] (3). Complexes 2 and 3 have been fully characterized by elemental analysis and NMR spectroscopy. The solid-state structure of 3 has been confirmed by X-ray diffraction analysis. Moreover, the activity of complex 3 as catalyst for the reaction of secondary amines with CO2 (3¿bar) and hydrosilanes has been studied. The outcomes of these catalytic studies show that under these conditions complex 3 promotes the selective formation of silylcarbamates.

Idioma: Inglés

DOI: 10.1016/j.jorganchem.2019.06.010

Año: 2019

Publicado en: Journal of Organometallic Chemistry 897 (2019), 50-56 [25 pp.]
ISSN: 0022-328X

Factor impacto JCR: 2.304 (2019)

Categ. JCR: CHEMISTRY, ORGANIC rank: 26 / 57 = 0.456 (2019) - Q2 - T2
Categ. JCR: CHEMISTRY, INORGANIC & NUCLEAR rank: 20 / 45 = 0.444 (2019) - Q2 - T2

Factor impacto SCIMAGO: 0.506 - Materials Chemistry (Q2) - Inorganic Chemistry (Q2) - Physical and Theoretical Chemistry (Q2) - Organic Chemistry (Q2) - Biochemistry (Q3)

Financiación: info:eu-repo/grantAgreement/ES/DGA-FSE/E42-17R
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-67366-P

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Química Inorgánica (Dpto. Química Inorgánica)
Área (Departamento): Área Química Física (Dpto. Química Física)