000089962 001__ 89962
000089962 005__ 20200716101525.0
000089962 0247_ $$2doi$$a10.1021/acssuschemeng.9b02105
000089962 0248_ $$2sideral$$a112579
000089962 037__ $$aART-2019-112579
000089962 041__ $$aeng
000089962 100__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, Alejandro$$uUniversidad de Zaragoza
000089962 245__ $$aGlycerol-derived Solvents: Synthesis and properties of symmetric glyceryl diethers
000089962 260__ $$c2019
000089962 5060_ $$aAccess copy available to the general public$$fUnrestricted
000089962 5203_ $$aHerein we report a systematic study of the synthesis of symmetric glyceryl diethers from epichlorohydrin and different alcohols. Several inexpensive alkaline hydroxides were tested, and total conversions of epichlorohydrin were achieved. Although high yields of the desired products were possible, the final selectivity of the reaction depends strongly on the alcohol used. Eleven symmetric glyceryl diethers were prepared employing this synthetic methodology and, in order to determine their usefulness as solvents, their physicochemical properties (density, dielectric permittivity, refractive index, viscosity, surface tension, and boiling point) were measured and compared with those for similar conventional solvents. The results obtained prove the utility of these compounds as a green alternative to solvents obtained from nonrenewable sources.
000089962 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E37-17R$$9info:eu-repo/grantAgreement/ES/MEC/FPU14-04338$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-093431-B-100
000089962 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000089962 592__ $$a1.766$$b2019
000089962 590__ $$a7.632$$b2019
000089962 593__ $$aChemical Engineering (miscellaneous)$$c2019$$dQ1
000089962 591__ $$aENGINEERING, CHEMICAL$$b8 / 143 = 0.056$$c2019$$dQ1$$eT1
000089962 593__ $$aRenewable Energy, Sustainability and the Environment$$c2019$$dQ1
000089962 591__ $$aGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY$$b4 / 41 = 0.098$$c2019$$dQ1$$eT1
000089962 593__ $$aEnvironmental Chemistry$$c2019$$dQ1
000089962 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b25 / 177 = 0.141$$c2019$$dQ1$$eT1
000089962 593__ $$aChemistry (miscellaneous)$$c2019$$dQ1
000089962 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000089962 700__ $$0(orcid)0000-0002-6751-6306$$aPérez, Pascual$$uUniversidad de Zaragoza
000089962 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral, José A.$$uUniversidad de Zaragoza
000089962 700__ $$0(orcid)0000-0003-1199-2087$$aGarcía, José I.
000089962 700__ $$0(orcid)0000-0002-2676-8814$$aPires, Elisabet$$uUniversidad de Zaragoza
000089962 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000089962 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000089962 773__ $$g7, 15 (2019), 13004-13014$$pACS sustain. chem. & eng.$$tACS Sustainable Chemistry and Engineering$$x2168-0485
000089962 8564_ $$s539935$$uhttps://zaguan.unizar.es/record/89962/files/texto_completo.pdf$$yPostprint
000089962 8564_ $$s173220$$uhttps://zaguan.unizar.es/record/89962/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000089962 909CO $$ooai:zaguan.unizar.es:89962$$particulos$$pdriver
000089962 951__ $$a2020-07-16-09:30:01
000089962 980__ $$aARTICLE