000101514 001__ 101514 000101514 005__ 20240122154814.0 000101514 0247_ $$2doi$$a10.1039/d0cy00322k 000101514 0248_ $$2sideral$$a118315 000101514 037__ $$aART-2020-118315 000101514 041__ $$aeng 000101514 100__ $$aOchoa, E. 000101514 245__ $$aSynthesis and characterization of a supported Pd complex on carbon nanofibers for the selective decarbonylation of stearic acid to 1-heptadecene: the importance of subnanometric Pd dispersion 000101514 260__ $$c2020 000101514 5060_ $$aAccess copy available to the general public$$fUnrestricted 000101514 5203_ $$aProduction of linear alpha-olefins from renewable sources is gaining increasing attention because it allows the transition from the current petrochemical synthesis route to a more sustainable scenario. In this work, we describe the synthesis and characterization of an innovative catalyst based on a di-mu-chloro-bis[palladium(ii) anthranilate] complex highly dispersed by incipient wetness impregnation over acyl chlorinated carbon nanofibers. The subnanometric dispersion of the metal complex allowed higher catalytic efficiency for the selective decarbonylation of stearic acid to 1-heptadecene as compared to the reference homogenous catalyst. The best catalytic performance (90 mol% selectivity, 71 mol% conversion, and TON = 484) was achieved under mild reaction conditions (atmospheric pressure, 140 degrees C) with a Pd loading in solution of 0.14 mol%. The post-mortem catalyst characterization and the recyclability tests evidenced the high stability of the catalyst. The highly dispersed catalyst developed in this work provides new opportunities in the rational design of more efficient catalytic systems for the sustainable transformation of fatty acids. 000101514 536__ $$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/ENE2017-83854-R 000101514 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000101514 590__ $$a6.119$$b2020 000101514 591__ $$aCHEMISTRY, PHYSICAL$$b44 / 162 = 0.272$$c2020$$dQ2$$eT1 000101514 592__ $$a1.635$$b2020 000101514 593__ $$aCatalysis$$c2020$$dQ1 000101514 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000101514 700__ $$aHenao, W. 000101514 700__ $$0(orcid)0000-0003-1812-3175$$aFuertes, S. 000101514 700__ $$aTorres, D. 000101514 700__ $$avan Haasterech, T. 000101514 700__ $$aScott, E. 000101514 700__ $$aBitter, H. 000101514 700__ $$aSuelves, I. 000101514 700__ $$aPinilla, J.L. 000101514 773__ $$g10, 9 (2020), 2970-2985$$pCATALYSIS SCIENCE & TECHNOLOGY$$tCatalysis Science and Technology$$x2044-4753 000101514 8564_ $$s1596445$$uhttps://zaguan.unizar.es/record/101514/files/texto_completo.pdf$$yPostprint 000101514 8564_ $$s1242910$$uhttps://zaguan.unizar.es/record/101514/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000101514 909CO $$ooai:zaguan.unizar.es:101514$$particulos$$pdriver 000101514 951__ $$a2024-01-22-15:33:46 000101514 980__ $$aARTICLE