000101610 001__ 101610
000101610 005__ 20220426091131.0
000101610 0247_ $$2doi$$a10.1002/ejic.202000356
000101610 0248_ $$2sideral$$a118212
000101610 037__ $$aART-2020-118212
000101610 041__ $$aeng
000101610 100__ $$aMollar-Cuni, A.
000101610 245__ $$aA Platinum Molecular Complex Immobilised on the Surface of Graphene as Active Catalyst in Alkyne Hydrosilylation
000101610 260__ $$c2020
000101610 5060_ $$aAccess copy available to the general public$$fUnrestricted
000101610 5203_ $$aA platinum complex bearing a N-heterocyclic carbene (NHC) ligand functionalised with a pyrene-tag is immobilised onto the surface of reduced graphene oxide (rGO). The hybrid material composed of an organometallic complex and a graphene derivative is ready available in a single-step process under mild reaction conditions. This methodology preserves the inherent properties of the active catalytic centre and the support. The platinum hybrid material is an efficient catalyst in hydrosilylation of alkynes and can be recycled and reused without significant loss of activity due to its high stability. Interestingly, the catalytic activity of the platinum complex is not affected by diffusion problems after immobilisation. The influence of graphene in hydrosilylation of alkynes is discussed in terms of activity and selectivity.
000101610 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragón$$9info:eu-repo/grantAgreement/ES/DGA-FEDER/E31-17R$$9info:eu-repo/grantAgreement/ES/MICIU/RTI2018-098237-B-C22$$9info:eu-repo/grantAgreement/ES/MICIU/RTI2018-098903-J-I00
000101610 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000101610 590__ $$a2.524$$b2020
000101610 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b20 / 45 = 0.444$$c2020$$dQ2$$eT2
000101610 592__ $$a0.667$$b2020
000101610 593__ $$aInorganic Chemistry$$c2020$$dQ2
000101610 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000101610 700__ $$aBorja, P.
000101610 700__ $$0(orcid)0000-0001-9193-3874$$aMartin, S.$$uUniversidad de Zaragoza
000101610 700__ $$0(orcid)0000-0002-0154-9682$$aGuisado-Barrios, G.
000101610 700__ $$aMata, J.A.
000101610 7102_ $$12012$$2755$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Química Física
000101610 773__ $$g2020, 45 (2020), 4254-4262$$pEur. j. inorg. chem.$$tEuropean Journal of Inorganic Chemistry$$x1434-1948
000101610 8564_ $$s1152534$$uhttps://zaguan.unizar.es/record/101610/files/texto_completo.pdf$$yPostprint
000101610 8564_ $$s1095592$$uhttps://zaguan.unizar.es/record/101610/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000101610 909CO $$ooai:zaguan.unizar.es:101610$$particulos$$pdriver
000101610 951__ $$a2022-04-26-08:51:53
000101610 980__ $$aARTICLE