000101614 001__ 101614 000101614 005__ 20210902121716.0 000101614 0247_ $$2doi$$a10.1016/j.fuel.2020.118033 000101614 0248_ $$2sideral$$a117708 000101614 037__ $$aART-2020-117708 000101614 041__ $$aeng 000101614 100__ $$0(orcid)0000-0002-9579-2551$$aAdánez-Rubio, I. 000101614 245__ $$aEffect of H2S on the S-PAH formation during ethylene pyrolysis 000101614 260__ $$c2020 000101614 5060_ $$aAccess copy available to the general public$$fUnrestricted 000101614 5203_ $$aThe effect of the H2S presence on the formation of six different sulphurated polycyclic hydrocarbons (S-PAH), during the pyrolysis of ethylene-H2S mixtures, has been studied in a tubular flow reactor installation. Experiments with different inlet H2S concentrations (0.3, 0.5 and 1%) and temperatures of reaction (between 1075 and 1475 K) have been carried out. The 16 compounds that the Environmental Protection Agency (EPA) has stated as EPA-PAH priority pollutants were also analysed. EPA-PAH compounds were the majority of quantified PAH, and also S-PAH were found and quantified. For temperatures studied, the S-PAH/EPA-PAH ratio values showed a maximum value at 1075 K and a minimum value at 1175 K. With respect to the effect of the inlet concentration of H2S, the S-PAH/EPA-PAH ratio values increased with the increase of the H2S concentration. 000101614 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/T22-20R$$9info:eu-repo/grantAgreement/ES/MCIU/RTI2018-098856-B-100$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/CTQ2015-65226-R$$9info:eu-repo/grantAgreement/ES/MINECO/FJCI-2015-23862 000101614 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/ 000101614 590__ $$a6.609$$b2020 000101614 591__ $$aENGINEERING, CHEMICAL$$b20 / 143 = 0.14$$c2020$$dQ1$$eT1 000101614 591__ $$aENERGY & FUELS$$b27 / 114 = 0.237$$c2020$$dQ1$$eT1 000101614 592__ $$a1.56$$b2020 000101614 593__ $$aChemical Engineering (miscellaneous)$$c2020$$dQ1 000101614 593__ $$aOrganic Chemistry$$c2020$$dQ1 000101614 593__ $$aFuel Technology$$c2020$$dQ1 000101614 593__ $$aEnergy Engineering and Power Technology$$c2020$$dQ1 000101614 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000101614 700__ $$0(orcid)0000-0001-5426-6486$$aMillera, Á.$$uUniversidad de Zaragoza 000101614 700__ $$0(orcid)0000-0002-5420-0943$$aBilbao, R.$$uUniversidad de Zaragoza 000101614 700__ $$0(orcid)0000-0003-4679-5761$$aAlzueta, M.U.$$uUniversidad de Zaragoza 000101614 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química 000101614 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente 000101614 773__ $$g276 (2020), 118033 [7 pp.]$$pFuel$$tFuel$$x0016-2361 000101614 8564_ $$s834094$$uhttps://zaguan.unizar.es/record/101614/files/texto_completo.pdf$$yPostprint 000101614 8564_ $$s1312927$$uhttps://zaguan.unizar.es/record/101614/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000101614 909CO $$ooai:zaguan.unizar.es:101614$$particulos$$pdriver 000101614 951__ $$a2021-09-02-09:24:31 000101614 980__ $$aARTICLE