000101628 001__ 101628 000101628 005__ 20240126182118.0 000101628 0247_ $$2doi$$a10.1016/j.talanta.2020.122079 000101628 0248_ $$2sideral$$a123966 000101628 037__ $$aART-2021-123966 000101628 041__ $$aeng 000101628 100__ $$aJaén, J. 000101628 245__ $$aAtmospheric Solids Analysis Probe (ASAP) and Atmospheric Pressure Gas Chromatography (APGC) coupled to Quadrupole Time of Flight Mass Spectrometry (QTOF-MS) as alternative techniques to trace aromatic markers of mineral oils in food packaging 000101628 260__ $$c2021 000101628 5060_ $$aAccess copy available to the general public$$fUnrestricted 000101628 5203_ $$aThe aim of this work was to select and identify the best markers of aromatic hydrocarbon mineral oil (MOAH) in food packaging. For this purpose, a series of mineral oils was initially analysed. Polycyclic Aromatic Hydrocarbons (PAHs) and the alkylated isomers of Methylnaphthalene (MNS), Diisopropylnaphtalene (DIPNs), Dibenzothiophenes (DBTS), Methyldibenzothiophene (MDBTs), Dimethyldibenzothiophenes (DMDBTs) and Benzonaphthiophenes (BNTS) were then explored. Their presence was confirmed by direct analysis of several mineral oils by Atmospheric Solids Analysis Probe Quadrupole-Time of Flight Mass Spectrometry (ASAP-QTOF-MS). Atmospheric Pressure Gas Chromatography Quadrupole-Time of Flight Mass Spectrometry (APGC-QTOF-MS) was used to confirm the markers in different samples of oils, recycled PET (rPET), recycled cardboard and packaging of couscous and semolina to confirm the contamination. 27 markers were found in the mineral oil samples, 22 of them in rPET, 8 in recycled board and no MOAH were found in packaging of couscous and semolina. 000101628 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/T53-20R 000101628 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/ 000101628 590__ $$a6.556$$b2021 000101628 592__ $$a0.983$$b2021 000101628 591__ $$aCHEMISTRY, ANALYTICAL$$b11 / 87 = 0.126$$c2021$$dQ1$$eT1 000101628 593__ $$aSpectroscopy$$c2021$$dQ1 000101628 593__ $$aAnalytical Chemistry$$c2021$$dQ1 000101628 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000101628 700__ $$0(orcid)0000-0001-8893-0963$$aDomeño, C.$$uUniversidad de Zaragoza 000101628 700__ $$0(orcid)0000-0002-3703-7902$$aAlfaro, P.$$uUniversidad de Zaragoza 000101628 700__ $$0(orcid)0000-0003-2685-5739$$aNerín, C.$$uUniversidad de Zaragoza 000101628 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica 000101628 7102_ $$12009$$2X$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cProy. investigación HVA 000101628 773__ $$g227 (2021), 122079 [9 pp.]$$pTalanta$$tTalanta$$x0039-9140 000101628 8564_ $$s1476430$$uhttps://zaguan.unizar.es/record/101628/files/texto_completo.pdf$$yVersión publicada 000101628 8564_ $$s2461370$$uhttps://zaguan.unizar.es/record/101628/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000101628 909CO $$ooai:zaguan.unizar.es:101628$$particulos$$pdriver 000101628 951__ $$a2024-01-26-18:17:21 000101628 980__ $$aARTICLE