000102203 001__ 102203
000102203 005__ 20230519145459.0
000102203 0247_ $$2doi$$a10.1007/s10854-021-05747-3
000102203 0248_ $$2sideral$$a124266
000102203 037__ $$aART-2021-124266
000102203 041__ $$aeng
000102203 100__ $$aRayes, A.
000102203 245__ $$aSynthesis, crystal structures, Hirshfeld surface analysis and physico-chemical characterization of two new ZnII and CdII halidometallates
000102203 260__ $$c2021
000102203 5060_ $$aAccess copy available to the general public$$fUnrestricted
000102203 5203_ $$aTwo new organic–inorganic hybrid materials, based on 1, 3-CycloHexaneBis-(Methyl Amine), abbreviated CHBMA, namely (H2CHBMA)ZnCl4·2H2O (CP1) and (H2CHBMA)CdI4·2H2O (CP2), have been synthesized under mild conditions in acidic media and characterized by single-crystal X-ray diffraction, spectroscopic techniques (13C NMR, FTIR, RAMAN) and thermal analysis. The crystal structures of the two compounds were solved by single-crystal X-ray diffraction methods. Both compounds show a 3-dimensional supramolecular structure directed by various interactions between tetrahalidometallate anions (ZnCl42-, CdI42-), water molecule and organic cations (H2CHBMA)2+. For both compounds, the cyclohexane ring of the template cation is in a chair conformation with the methylammonium substituent in the equatorial positions and the two terminal ammonium groups in a cis conformation but with two different orientations (upward for CP1 and downward for CP2) which influences the supramolecular architecture of the two structures. Hirshfeld surface analysis and the associated two-dimensional finger print plots were used to explore and quantify the intermolecular interactions in the crystals.
000102203 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000102203 590__ $$a2.779$$b2021
000102203 592__ $$a0.464$$b2021
000102203 594__ $$a4.2$$b2021
000102203 591__ $$aPHYSICS, APPLIED$$b80 / 161 = 0.497$$c2021$$dQ2$$eT2
000102203 591__ $$aENGINEERING, ELECTRICAL & ELECTRONIC$$b133 / 277 = 0.48$$c2021$$dQ2$$eT2
000102203 591__ $$aPHYSICS, CONDENSED MATTER$$b40 / 69 = 0.58$$c2021$$dQ3$$eT2
000102203 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b220 / 345 = 0.638$$c2021$$dQ3$$eT2
000102203 593__ $$aAtomic and Molecular Physics, and Optics$$c2021$$dQ2
000102203 593__ $$aBioengineering$$c2021$$dQ2
000102203 593__ $$aCondensed Matter Physics$$c2021$$dQ2
000102203 593__ $$aBiophysics$$c2021$$dQ2
000102203 593__ $$aElectronic, Optical and Magnetic Materials$$c2021$$dQ2
000102203 593__ $$aBiomaterials$$c2021$$dQ2
000102203 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000102203 700__ $$aMoncer, M.
000102203 700__ $$0(orcid)0000-0002-5881-9698$$aAra, I.$$uUniversidad de Zaragoza
000102203 700__ $$aDege, N.
000102203 700__ $$aAyed, B.
000102203 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000102203 773__ $$g32 (2021), 10890–10905$$pJ. mater. sci., Mater. electron.$$tJournal of Materials Science: Materials in Electronics$$x0957-4522
000102203 8564_ $$s2824206$$uhttps://zaguan.unizar.es/record/102203/files/texto_completo.pdf$$yVersión publicada
000102203 8564_ $$s1932580$$uhttps://zaguan.unizar.es/record/102203/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000102203 909CO $$ooai:zaguan.unizar.es:102203$$particulos$$pdriver
000102203 951__ $$a2023-05-18-14:54:34
000102203 980__ $$aARTICLE