102203 20230519145459.0 doi 10.1007/s10854-021-05747-3 sideral 124266 ART-2021-124266 eng Rayes, A. Synthesis, crystal structures, Hirshfeld surface analysis and physico-chemical characterization of two new ZnII and CdII halidometallates 2021 Access copy available to the general public Unrestricted Two new organic–inorganic hybrid materials, based on 1, 3-CycloHexaneBis-(Methyl Amine), abbreviated CHBMA, namely (H2CHBMA)ZnCl4·2H2O (CP1) and (H2CHBMA)CdI4·2H2O (CP2), have been synthesized under mild conditions in acidic media and characterized by single-crystal X-ray diffraction, spectroscopic techniques (13C NMR, FTIR, RAMAN) and thermal analysis. The crystal structures of the two compounds were solved by single-crystal X-ray diffraction methods. Both compounds show a 3-dimensional supramolecular structure directed by various interactions between tetrahalidometallate anions (ZnCl42-, CdI42-), water molecule and organic cations (H2CHBMA)2+. For both compounds, the cyclohexane ring of the template cation is in a chair conformation with the methylammonium substituent in the equatorial positions and the two terminal ammonium groups in a cis conformation but with two different orientations (upward for CP1 and downward for CP2) which influences the supramolecular architecture of the two structures. Hirshfeld surface analysis and the associated two-dimensional finger print plots were used to explore and quantify the intermolecular interactions in the crystals. info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 2.779 2021 PHYSICS, APPLIED 80 / 161 = 0.497 2021 Q2 T2 ENGINEERING, ELECTRICAL & ELECTRONIC 133 / 277 = 0.48 2021 Q2 T2 PHYSICS, CONDENSED MATTER 40 / 69 = 0.58 2021 Q3 T2 MATERIALS SCIENCE, MULTIDISCIPLINARY 220 / 345 = 0.638 2021 Q3 T2 0.464 2021 Atomic and Molecular Physics, and Optics 2021 Q2 Bioengineering 2021 Q2 Condensed Matter Physics 2021 Q2 Biophysics 2021 Q2 Electronic, Optical and Magnetic Materials 2021 Q2 Biomaterials 2021 Q2 4.2 2021 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Moncer, M. Ara, I. Universidad de Zaragoza (orcid)0000-0002-5881-9698 Dege, N. Ayed, B. 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 32 (2021), 10890–10905 J. mater. sci., Mater. electron. Journal of Materials Science: Materials in Electronics 0957-4522 2824206 http://zaguan.unizar.es/record/102203/files/texto_completo.pdf Versión publicada 1932580 http://zaguan.unizar.es/record/102203/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:102203 articulos driver 2023-05-18-14:54:34 ARTICLE