000102254 001__ 102254
000102254 005__ 20210902121744.0
000102254 0247_ $$2doi$$a10.1016/j.sab.2020.105883
000102254 0248_ $$2sideral$$a118431
000102254 037__ $$aART-2020-118431
000102254 041__ $$aeng
000102254 100__ $$0(orcid)0000-0002-4169-0357$$aLaborda, Francisco$$uUniversidad de Zaragoza
000102254 245__ $$aAbout detectability and limits of detection in single particle inductively coupled plasma mass spectrometry
000102254 260__ $$c2020
000102254 5060_ $$aAccess copy available to the general public$$fUnrestricted
000102254 5203_ $$aSingle particle inductively coupled plasma mass spectrometry (SP-ICP-MS) offers unique features for the detection of particles, as well as for their quantification and size characterization. The detection capabilities of SP-ICP-MS are therefore not only limited to the concentration domains (of particles and dissolved related species), but also to the mass of element per particle and particle size domains. Discrimination and detection of particle events, based on the use of robust limits of decision (also known as critical values), and the estimation of the limits of detection in the different domains, require standardized metrological approaches that have not been clearly established yet. As a consequence, harmonized approaches and expressions to allow reliable comparisons between methods and instruments, as well as to process SP-ICP-MS data, are required. This paper is an attempt to summarize and review the different approaches applied up to now in relation to the detectability in SP-ICP-MS, and highlight the peculiarities of this topic in SP-ICP-MS. A holistic approach with criteria and expressions for the estimation of the different critical values and limits of detection in terms of the different instrumental and experimental parameters involved is proposed. Additionally, a calculation tool for estimating and predicting critical values and limits of detection under different experimental conditions is also included.
000102254 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-096111-B-100
000102254 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000102254 590__ $$a3.752$$b2020
000102254 591__ $$aSPECTROSCOPY$$b8 / 43 = 0.186$$c2020$$dQ1$$eT1
000102254 592__ $$a0.793$$b2020
000102254 593__ $$aAnalytical Chemistry$$c2020$$dQ1
000102254 593__ $$aSpectroscopy$$c2020$$dQ1
000102254 593__ $$aInstrumentation$$c2020$$dQ1
000102254 593__ $$aAtomic and Molecular Physics, and Optics$$c2020$$dQ1
000102254 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000102254 700__ $$0(orcid)0000-0002-9181-2105$$aGimenez-Ingalaturre, Ana C.$$uUniversidad de Zaragoza
000102254 700__ $$0(orcid)0000-0001-5382-0561$$aBolea, Eduardo$$uUniversidad de Zaragoza
000102254 700__ $$0(orcid)0000-0002-4070-8607$$aCastillo, Juan R.$$uUniversidad de Zaragoza
000102254 7102_ $$12009$$2750$$aUniversidad de Zaragoza$$bDpto. Química Analítica$$cÁrea Química Analítica
000102254 773__ $$g169 (2020), 105883 1-11$$pSpectrochim. acta, Part B: Atom. spectrosc.$$tSpectrochimica Acta - Part B Atomic Spectroscopy$$x0584-8547
000102254 8564_ $$s8515371$$uhttps://zaguan.unizar.es/record/102254/files/texto_completo.pdf$$yPostprint
000102254 8564_ $$s1532049$$uhttps://zaguan.unizar.es/record/102254/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000102254 909CO $$ooai:zaguan.unizar.es:102254$$particulos$$pdriver
000102254 951__ $$a2021-09-02-09:44:30
000102254 980__ $$aARTICLE