000106263 001__ 106263
000106263 005__ 20210706112730.0
000106263 0247_ $$2doi$$a10.1039/c5ra10191c
000106263 0248_ $$2sideral$$a91567
000106263 037__ $$aART-2015-91567
000106263 041__ $$aeng
000106263 100__ $$aMartínez, A.V.
000106263 245__ $$aAn extremely highly recoverable clay-supported Pd nanoparticle catalyst for solvent-free Heck-Mizoroki reactions
000106263 260__ $$c2015
000106263 5060_ $$aAccess copy available to the general public$$fUnrestricted
000106263 5203_ $$aPalladium nanoparticles supported on LAPONITE®, a synthetic clay, are shown to constitute a highly robust and stable catalytic system for Heck–Mizoroki reactions carried out under solventless conditions. Both the preparation and the use of the catalyst are straightforward, allowing easy separation of the reaction products in pure form. In the case of the reaction between butyl acrylate and iodobenzene, up to 50 catalyst cycles can be performed before observing a noticeable decrease in activity. After reactivation of the catalyst by calcination, it can be further used for at least an additional 25 reactions. The stability of the catalyst seems to be related to the electronic density of the reacting alkene, as illustrated by the results obtained using the same catalyst with other alkenes.
000106263 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E11$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2011-28124-C02-01
000106263 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc$$uhttp://creativecommons.org/licenses/by-nc/3.0/es/
000106263 590__ $$a3.289$$b2015
000106263 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b48 / 163 = 0.294$$c2015$$dQ2$$eT1
000106263 592__ $$a0.947$$b2015
000106263 593__ $$aChemistry (miscellaneous)$$c2015$$dQ1
000106263 593__ $$aChemical Engineering (miscellaneous)$$c2015$$dQ1
000106263 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000106263 700__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, A.
000106263 700__ $$0(orcid)0000-0003-1199-2087$$aGarcía, J.I.
000106263 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral, J.A.$$uUniversidad de Zaragoza
000106263 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000106263 773__ $$g5, 74 (2015), 59983-59990$$pRSC ADVANCES$$tRSC Advances$$x2046-2069
000106263 8564_ $$s712362$$uhttps://zaguan.unizar.es/record/106263/files/texto_completo.pdf$$yVersión publicada
000106263 8564_ $$s2950385$$uhttps://zaguan.unizar.es/record/106263/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000106263 909CO $$ooai:zaguan.unizar.es:106263$$particulos$$pdriver
000106263 951__ $$a2021-07-06-09:50:05
000106263 980__ $$aARTICLE