000106587 001__ 106587
000106587 005__ 20210902121925.0
000106587 0247_ $$2doi$$a10.1039/d0ce00832j
000106587 0248_ $$2sideral$$a120303
000106587 037__ $$aART-2020-120303
000106587 041__ $$aeng
000106587 100__ $$0(orcid)0000-0002-7486-8502$$aGonzález, L.
000106587 245__ $$aThe combination of halogen and hydrogen bonding: a versatile tool in coordination chemistry
000106587 260__ $$c2020
000106587 5060_ $$aAccess copy available to the general public$$fUnrestricted
000106587 5203_ $$a4-Iodo-N-(4-pyridyl)benzamide (INPBA) and four derived coordination complexes were synthesized in order to explore the combination of halogen and hydrogen bonding interactions in coordination chemistry. An electron-withdrawing carbonyl group attached to the aromatic ring bearing an iodine atom has been introduced to increase its halogen bonding ability. Single crystal X-ray diffraction analyses ofINPBA, [Ag(INPBA)2]NO3(1), [ZnBr2(INPBA)2](2), [Zn(OCOPh)2(INPBA)2](3) and[HgI2(INPBA)]n(4) show the versatility of theINPBAbuilding block yielding a variety of different interesting structures. Iodine atom arrangement plays a key role by reinforcing and extending crystalline structures into diverse 3D supramolecular networksviaI¿O, I¿N, and I¿I halogen bonding interactions. Besides this, the overall supramolecular architecture of the coordination complexes is modulated by the N-H¿O, N-H¿Br, and C-H¿O hydrogen bonds formed by the carboxamide group. The combination of both, halogen and hydrogen bonds, allows very different coordination networks to be designed.
000106587 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragón$$9info:eu-repo/grantAgreement/ES/DGA-FEDER/E47-20R$$9info:eu-repo/grantAgreement/ES/MICINN/PGC2018-093761-B-C31$$9info:eu-repo/grantAgreement/ES/MINECO/MAT2017-84838-P$$9info:eu-repo/grantAgreement/ES/MINECO/PGC2018-097583-B-I00
000106587 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000106587 590__ $$a3.545$$b2020
000106587 591__ $$aCRYSTALLOGRAPHY$$b6 / 25 = 0.24$$c2020$$dQ1$$eT1
000106587 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b76 / 178 = 0.427$$c2020$$dQ2$$eT2
000106587 592__ $$a0.812$$b2020
000106587 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000106587 593__ $$aMaterials Science (miscellaneous)$$c2020$$dQ1
000106587 593__ $$aCondensed Matter Physics$$c2020$$dQ1
000106587 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000106587 700__ $$aGraus, S.$$uUniversidad de Zaragoza
000106587 700__ $$0(orcid)0000-0003-1141-5933$$aTejedor, R.M.$$uUniversidad de Zaragoza
000106587 700__ $$aChanthapally, A.
000106587 700__ $$0(orcid)0000-0001-9866-6633$$aSerrano, J.L.$$uUniversidad de Zaragoza
000106587 700__ $$0(orcid)0000-0001-7636-9187$$aUriel, S.$$uUniversidad de Zaragoza
000106587 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica
000106587 7102_ $$12012$$2X$$aUniversidad de Zaragoza$$bDpto. Química Física$$cÁrea Técnica. Lab. y Talleres
000106587 773__ $$g22, 36 (2020), 6010-6018$$pCrystEngComm$$tCRYSTENGCOMM$$x1466-8033
000106587 8564_ $$s1185880$$uhttps://zaguan.unizar.es/record/106587/files/texto_completo.pdf$$yPostprint
000106587 8564_ $$s1169377$$uhttps://zaguan.unizar.es/record/106587/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000106587 909CO $$ooai:zaguan.unizar.es:106587$$particulos$$pdriver
000106587 951__ $$a2021-09-02-10:50:37
000106587 980__ $$aARTICLE