000106608 001__ 106608
000106608 005__ 20210902121722.0
000106608 0247_ $$2doi$$a10.1039/d0nj02276d
000106608 0248_ $$2sideral$$a119659
000106608 037__ $$aART-2020-119659
000106608 041__ $$aeng
000106608 100__ $$aCernak, J.
000106608 245__ $$aField induced slow magnetic relaxation in a zig-zag chain-like Dy(iii) complex with the ligando-phenylenedioxydiacetato
000106608 260__ $$c2020
000106608 5060_ $$aAccess copy available to the general public$$fUnrestricted
000106608 5203_ $$aThe new complex [Dy(PDOA)(NO3)(H2O)(2)](n)center dot nH(2)O (1) (H(2)PDOA iso-phenylenedioxydiacetic acid) was isolated from the reaction of dysprosium(iii) nitrate and H(2)PDOA in a 1 : 1 molar ratio. Its crystal structure is formed of neutral zig-zag chains in which the nona-coordinated Dy(iii) atoms (O(9)donor set) are linked by PDOA ligands with a chelating-bridging coordination mode. DC and AC magnetic studies revealed that1behaves as a field-induced SMM with three relaxation channels. The derived values, considering the Orbach relaxation process, of the barrier to spin reversal and the extrapolated relaxation time areU/k(B)= 59.5 K and tau(0)= 6.3 x 10(-10)s, respectively.Ab initiocalculations support the experimental results.
000106608 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E11-20R$$9info:eu-repo/grantAgreement/ES/DGA/M4$$9info:eu-repo/grantAgreement/ES/MINECO-FEDER/PGC2018-093451-B-I00
000106608 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000106608 590__ $$a3.591$$b2020
000106608 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b75 / 178 = 0.421$$c2020$$dQ2$$eT2
000106608 592__ $$a0.692$$b2020
000106608 593__ $$aCatalysis$$c2020$$dQ1
000106608 593__ $$aMaterials Chemistry$$c2020$$dQ1
000106608 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000106608 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000106608 700__ $$aHarcarova, K.
000106608 700__ $$0(orcid)0000-0002-0444-996X$$aFalvello, L.R.$$uUniversidad de Zaragoza
000106608 700__ $$aDlhan, L.
000106608 700__ $$aTitis, J.
000106608 700__ $$aBoca, R.
000106608 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000106608 773__ $$g44, 31 (2020), 13458-13465$$pNew j. chem.$$tNEW JOURNAL OF CHEMISTRY$$x1144-0546
000106608 8564_ $$s1210197$$uhttps://zaguan.unizar.es/record/106608/files/texto_completo.pdf$$yPostprint
000106608 8564_ $$s1125273$$uhttps://zaguan.unizar.es/record/106608/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000106608 909CO $$ooai:zaguan.unizar.es:106608$$particulos$$pdriver
000106608 951__ $$a2021-09-02-09:29:07
000106608 980__ $$aARTICLE