000106636 001__ 106636 000106636 005__ 20210902121729.0 000106636 0247_ $$2doi$$a10.1021/acssuschemeng.0c04862 000106636 0248_ $$2sideral$$a120155 000106636 037__ $$aART-2020-120155 000106636 041__ $$aeng 000106636 100__ $$0(orcid)0000-0002-3256-2089$$aLeal-Duaso, A.$$uUniversidad de Zaragoza 000106636 245__ $$aSteps Forward toward the Substitution of Conventional Solvents in the Heck-Mizoroki Coupling Reaction: Glycerol-Derived Ethers and Deep Eutectic Solvents as Reaction Media 000106636 260__ $$c2020 000106636 5060_ $$aAccess copy available to the general public$$fUnrestricted 000106636 5203_ $$aGlycerol-derived ethers and their eutectic mixtures with two renewable ammonium salts (ChCl and N00Cl) are effectively used as new green solvents for the immobilization of PVP-Palladium nanoparticles. Those air-stable, selective, and recoverable catalytic systems are applied in the benchmark Heck-Mizoroki coupling reaction between iodobenzene and n-butyl acrylate in order to evaluate the influence of the different solvation properties of the solvent on the reaction results. The HBD ability (alpha acidity) of the solvent seems to play a crucial role in the reaction selectivity. 000106636 536__ $$9info:eu-repo/grantAgreement/ES/DGA-ERDF/E37-20R$$9info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-100$$9info:eu-repo/grantAgreement/ES/MEC/FPU14-04338 000106636 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000106636 590__ $$a8.198$$b2020 000106636 591__ $$aENGINEERING, CHEMICAL$$b14 / 143 = 0.098$$c2020$$dQ1$$eT1 000106636 591__ $$aGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY$$b6 / 44 = 0.136$$c2020$$dQ1$$eT1 000106636 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b29 / 178 = 0.163$$c2020$$dQ1$$eT1 000106636 592__ $$a1.877$$b2020 000106636 593__ $$aChemical Engineering (miscellaneous)$$c2020$$dQ1 000106636 593__ $$aRenewable Energy, Sustainability and the Environment$$c2020$$dQ1 000106636 593__ $$aEnvironmental Chemistry$$c2020$$dQ1 000106636 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1 000106636 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion 000106636 700__ $$0(orcid)0000-0003-1570-4257$$aMayoral, J.A.$$uUniversidad de Zaragoza 000106636 700__ $$0(orcid)0000-0002-2676-8814$$aPires, E.$$uUniversidad de Zaragoza 000106636 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica 000106636 773__ $$g8, 34 (2020), 13076-13084$$pACS sustain. chem. & eng.$$tACS Sustainable Chemistry and Engineering$$x2168-0485 000106636 8564_ $$s680549$$uhttps://zaguan.unizar.es/record/106636/files/texto_completo.pdf$$yPostprint 000106636 8564_ $$s1526962$$uhttps://zaguan.unizar.es/record/106636/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint 000106636 909CO $$ooai:zaguan.unizar.es:106636$$particulos$$pdriver 000106636 951__ $$a2021-09-02-09:34:36 000106636 980__ $$aARTICLE