106636 20210902121729.0 doi 10.1021/acssuschemeng.0c04862 sideral 120155 ART-2020-120155 eng Leal-Duaso, A. Universidad de Zaragoza (orcid)0000-0002-3256-2089 Steps Forward toward the Substitution of Conventional Solvents in the Heck-Mizoroki Coupling Reaction: Glycerol-Derived Ethers and Deep Eutectic Solvents as Reaction Media 2020 Access copy available to the general public Unrestricted Glycerol-derived ethers and their eutectic mixtures with two renewable ammonium salts (ChCl and N00Cl) are effectively used as new green solvents for the immobilization of PVP-Palladium nanoparticles. Those air-stable, selective, and recoverable catalytic systems are applied in the benchmark Heck-Mizoroki coupling reaction between iodobenzene and n-butyl acrylate in order to evaluate the influence of the different solvation properties of the solvent on the reaction results. The HBD ability (alpha acidity) of the solvent seems to play a crucial role in the reaction selectivity. info:eu-repo/grantAgreement/ES/DGA-ERDF/E37-20R info:eu-repo/grantAgreement/ES/MCIU/RTI2018-093431-B-100 info:eu-repo/grantAgreement/ES/MEC/FPU14-04338 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 8.198 2020 ENGINEERING, CHEMICAL 14 / 143 = 0.098 2020 Q1 T1 GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY 6 / 44 = 0.136 2020 Q1 T1 CHEMISTRY, MULTIDISCIPLINARY 29 / 178 = 0.163 2020 Q1 T1 1.877 2020 Chemical Engineering (miscellaneous) 2020 Q1 Renewable Energy, Sustainability and the Environment 2020 Q1 Environmental Chemistry 2020 Q1 Chemistry (miscellaneous) 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Mayoral, J.A. Universidad de Zaragoza (orcid)0000-0003-1570-4257 Pires, E. Universidad de Zaragoza (orcid)0000-0002-2676-8814 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 8, 34 (2020), 13076-13084 ACS sustain. chem. & eng. ACS Sustainable Chemistry and Engineering 2168-0485 680549 http://zaguan.unizar.es/record/106636/files/texto_completo.pdf Postprint 1526962 http://zaguan.unizar.es/record/106636/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:106636 articulos driver 2021-09-02-09:34:36 ARTICLE