000106691 001__ 106691 000106691 005__ 20230519145449.0 000106691 0247_ $$2doi$$a10.3390/membranes11070472 000106691 0248_ $$2sideral$$a124471 000106691 037__ $$aART-2021-124471 000106691 041__ $$aeng 000106691 100__ $$aJuárez, Ester 000106691 245__ $$aPolymer–ceramic composite membranes for water removal in membrane reactors 000106691 260__ $$c2021 000106691 5060_ $$aAccess copy available to the general public$$fUnrestricted 000106691 5203_ $$aMethanol can be obtained through CO2 hydrogenation in a membrane reactor with higher yield or lower pressure than in a conventional packed bed reactor. In this study, we explore a new kind of membrane with the potential suitability for such membrane reactors. Silicone–ceramic composite membranes are synthetized and characterized for their capability to selectively remove water from a mixture containing hydrogen, CO2, and water at temperatures typical for methanol synthesis. We show that this membrane can achieve selective permeation of water under such harsh conditions, and thus is an alternative candidate for use in membrane reactors for processes where water is one of the products and the yield is limited by thermodynamic equilibrium. 000106691 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-76533-R$$9info:eu-repo/grantAgreement/ES/MINECO/PID2019-106196RB-I00 000106691 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/ 000106691 590__ $$a4.562$$b2021 000106691 592__ $$a0.517$$b2021 000106691 594__ $$a3.7$$b2021 000106691 591__ $$aPOLYMER SCIENCE$$b21 / 90 = 0.233$$c2021$$dQ1$$eT1 000106691 593__ $$aProcess Chemistry and Technology$$c2021$$dQ2 000106691 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b132 / 345 = 0.383$$c2021$$dQ2$$eT2 000106691 593__ $$aChemical Engineering (miscellaneous)$$c2021$$dQ2 000106691 591__ $$aCHEMISTRY, PHYSICAL$$b69 / 165 = 0.418$$c2021$$dQ2$$eT2 000106691 591__ $$aENGINEERING, CHEMICAL$$b47 / 143 = 0.329$$c2021$$dQ2$$eT1 000106691 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion 000106691 700__ $$0(orcid)0000-0003-1940-9597$$aLasobras Laguna, Javier$$uUniversidad de Zaragoza 000106691 700__ $$0(orcid)0000-0002-7488-6196$$aSoler, Jaime 000106691 700__ $$0(orcid)0000-0002-2494-102X$$aHerguido, Javier$$uUniversidad de Zaragoza 000106691 700__ $$0(orcid)0000-0001-9022-2835$$aMenéndez, Miguel$$uUniversidad de Zaragoza 000106691 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química 000106691 773__ $$g11, 472 (2021), [9 pp.]$$pMembranes$$tMembranes$$x2077-0375 000106691 8564_ $$s1739262$$uhttps://zaguan.unizar.es/record/106691/files/texto_completo.pdf$$yVersión publicada 000106691 8564_ $$s2789796$$uhttps://zaguan.unizar.es/record/106691/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000106691 909CO $$ooai:zaguan.unizar.es:106691$$particulos$$pdriver 000106691 951__ $$a2023-05-18-14:42:43 000106691 980__ $$aARTICLE