106691 20230519145449.0 doi 10.3390/membranes11070472 sideral 124471 ART-2021-124471 eng Juárez, Ester Polymer–ceramic composite membranes for water removal in membrane reactors 2021 Access copy available to the general public Unrestricted Methanol can be obtained through CO2 hydrogenation in a membrane reactor with higher yield or lower pressure than in a conventional packed bed reactor. In this study, we explore a new kind of membrane with the potential suitability for such membrane reactors. Silicone–ceramic composite membranes are synthetized and characterized for their capability to selectively remove water from a mixture containing hydrogen, CO2, and water at temperatures typical for methanol synthesis. We show that this membrane can achieve selective permeation of water under such harsh conditions, and thus is an alternative candidate for use in membrane reactors for processes where water is one of the products and the yield is limited by thermodynamic equilibrium. info:eu-repo/grantAgreement/ES/MINECO/CTQ2016-76533-R info:eu-repo/grantAgreement/ES/MINECO/PID2019-106196RB-I00 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 4.562 2021 POLYMER SCIENCE 21 / 90 = 0.233 2021 Q1 T1 MATERIALS SCIENCE, MULTIDISCIPLINARY 132 / 345 = 0.383 2021 Q2 T2 CHEMISTRY, PHYSICAL 69 / 165 = 0.418 2021 Q2 T2 ENGINEERING, CHEMICAL 47 / 143 = 0.329 2021 Q2 T1 0.517 2021 Process Chemistry and Technology 2021 Q2 Chemical Engineering (miscellaneous) 2021 Q2 3.7 2021 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Lasobras Laguna, Javier Universidad de Zaragoza (orcid)0000-0003-1940-9597 Soler, Jaime (orcid)0000-0002-7488-6196 Herguido, Javier Universidad de Zaragoza (orcid)0000-0002-2494-102X Menéndez, Miguel Universidad de Zaragoza (orcid)0000-0001-9022-2835 5005 555 Universidad de Zaragoza Dpto. Ing.Quím.Tecnol.Med.Amb. Área Ingeniería Química 11, 472 (2021), [9 pp.] Membranes Membranes 2077-0375 1739262 http://zaguan.unizar.es/record/106691/files/texto_completo.pdf Versión publicada 2789796 http://zaguan.unizar.es/record/106691/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:106691 articulos driver 2023-05-18-14:42:43 ARTICLE