000107377 001__ 107377 000107377 005__ 20210930091334.0 000107377 0247_ $$2doi$$a10.1002/chem.201605655 000107377 0248_ $$2sideral$$a97350 000107377 037__ $$aART-2017-97350 000107377 041__ $$aeng 000107377 100__ $$0(orcid)0000-0002-2492-625X$$aBaya, Miguel$$uUniversidad de Zaragoza 000107377 245__ $$aGold(I) Fluorohalides: Theory and Experiment 000107377 260__ $$c2017 000107377 5060_ $$aAccess copy available to the general public$$fUnrestricted 000107377 5203_ $$aThe anionic trifluoromethylgold(I) derivatives [CF3AuX]−, which have been prepared and isolated as their [PPh4]+ salts in good yield, undergo thermally induced difluorocarbene extrusion in the gas phase, giving rise to the mixed gold(I) fluorohalide complexes [F−Au−X]− (X=Cl, Br, I). These triatomic species have been detected by tandem mass spectrometry (MS2) experiments and their properties have been analyzed by DFT methods. The CF2 extrusion mechanism from the Au−CF3 moiety serves as a model for the CF2 insertion into the Au−F bond, since both reactivity channels are connected by the microreversibility principle. 000107377 536__ $$9info:eu-repo/grantAgreement/ES/DGA/E21$$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67461-P 000107377 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/ 000107377 590__ $$a5.16$$b2017 000107377 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b37 / 171 = 0.216$$c2017$$dQ1$$eT1 000107377 592__ $$a2.265$$b2017 000107377 593__ $$aChemistry (miscellaneous)$$c2017$$dQ1 000107377 655_4 $$ainfo:eu-repo/semantics/conferenceObject$$vinfo:eu-repo/semantics/publishedVersion 000107377 700__ $$0(orcid)0000-0003-2260-676X$$aPérez-Bitrián, Alberto$$uUniversidad de Zaragoza 000107377 700__ $$0(orcid)0000-0002-7920-4000$$aMartínez-Salvador, Sonia 000107377 700__ $$0(orcid)0000-0003-0341-7699$$aCasas, José María$$uUniversidad de Zaragoza 000107377 700__ $$0(orcid)0000-0001-9045-5102$$aMenjón, Babil 000107377 700__ $$0(orcid)0000-0003-3514-2570$$aOrduna, Jesús$$uUniversidad de Zaragoza 000107377 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica 000107377 7102_ $$12013$$2765$$aUniversidad de Zaragoza$$bDpto. Química Orgánica$$cÁrea Química Orgánica 000107377 773__ $$g23, 7 (2017), 1512-1515$$pChemistry (Weinh.)$$tChemistry - A European Journal$$x0947-6539 000107377 8564_ $$s579436$$uhttps://zaguan.unizar.es/record/107377/files/texto_completo.pdf$$yVersión publicada 000107377 8564_ $$s2830290$$uhttps://zaguan.unizar.es/record/107377/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada 000107377 909CO $$ooai:zaguan.unizar.es:107377$$particulos$$pdriver 000107377 951__ $$a2021-09-30-08:21:19 000107377 980__ $$aARTICLE