107377 20210930091334.0 doi 10.1002/chem.201605655 sideral 97350 ART-2017-97350 eng Baya, Miguel Universidad de Zaragoza (orcid)0000-0002-2492-625X Gold(I) Fluorohalides: Theory and Experiment 2017 The anionic trifluoromethylgold(I) derivatives [CF3AuX]−, which have been prepared and isolated as their [PPh4]+ salts in good yield, undergo thermally induced difluorocarbene extrusion in the gas phase, giving rise to the mixed gold(I) fluorohalide complexes [F−Au−X]− (X=Cl, Br, I). These triatomic species have been detected by tandem mass spectrometry (MS2) experiments and their properties have been analyzed by DFT methods. The CF2 extrusion mechanism from the Au−CF3 moiety serves as a model for the CF2 insertion into the Au−F bond, since both reactivity channels are connected by the microreversibility principle. Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/DGA/E21 info:eu-repo/grantAgreement/ES/MINECO/CTQ2015-67461-P info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 5.16 2017 CHEMISTRY, MULTIDISCIPLINARY 37 / 171 = 0.216 2017 Q1 T1 2.265 2017 Chemistry (miscellaneous) 2017 Q1 info:eu-repo/semantics/conferenceObject info:eu-repo/semantics/publishedVersion Pérez-Bitrián, Alberto Universidad de Zaragoza (orcid)0000-0003-2260-676X Martínez-Salvador, Sonia (orcid)0000-0002-7920-4000 Casas, José María Universidad de Zaragoza (orcid)0000-0003-0341-7699 Menjón, Babil (orcid)0000-0001-9045-5102 Orduna, Jesús Universidad de Zaragoza (orcid)0000-0003-3514-2570 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 2013 765 Universidad de Zaragoza Dpto. Química Orgánica Área Química Orgánica 23, 7 (2017), 1512-1515 Chemistry (Weinh.) Chemistry - A European Journal 0947-6539 579436 http://zaguan.unizar.es/record/107377/files/texto_completo.pdf Versión publicada 2830290 http://zaguan.unizar.es/record/107377/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:107377 articulos driver 2021-09-30-08:21:19 ARTICLE