107453 20240122154814.0 doi 10.1021/acs.organomet.0c00510 sideral 121163 ART-2020-121163 eng Jaime, S. Cyclometalated NHCs Pt(II) Compounds with Chelating P^P and S^S Ligands: From Blue to White Luminescence 2020 Access copy available to the general public Unrestricted Ionic [Pt(C^C*A/B)(P^P)]PF6 and neutral [Pt(C^C*A/B)(S^S)] complexes were designed and synthesized containing cyclometalated N-heterocyclic carbenes (C^C*A/B) and diphosphines (P^P: dpfppe, dcypm) or dithiocarbamates (S^S: dmdtc, pdtc) as chelating ligands. Their structural and spectroscopic properties were investigated and found to be dependent on both cyclometalated (C^C*A/B) and ancillary (P^P, S^S) ligands. The photophysical and computational studies for the [Pt(C^C*A/B)(P^P)]+complexes disclose the nature of the low-lying electronic transitions to be mainly intraligand charge transfer [ILCT (C^C*A/B)] with some contribution of ligand-to-ligand charge transfer (LL''CT) or ligand-to metal charge transfer (LMCT) for the dpfppe or dcypm derivatives, respectively. The blue and cyan emissions of PMMA films doped with the [Pt(C^C*A/B)(P^P)]+ complexes exhibited very high quantum yields (QYs) reaching up to ~90%. However, the low-energy absorptions and emissions of the [Pt(C^C*A/B)(S^S)] complexes in solution (rt or 77 K) arise from mixed ILCT [C^C*A/B]/MLCT [dp(Pt) ¿ p*(C^C*A/B)] excited states, showing no change with the different S^S ligands. In solid-state and in doped films, these dithiocarbamate complexes, excluding 8B, display dual emissions with the high-energy vibronic band (3ILCT /3MLCT) appearing together with an additional low-energy structureless band. The latter is attributed to 3pp* transitions originated from p-stacked aggregates, as reported in the X-ray structure of 7A. Thus, white light emissions can be obtained with photo- and colorimetric values lying inside the stipulated limits for general lighting applications; yet, they display low QY. Copyright info:eu-repo/grantAgreement/ES/CSIC/2018801070-PIE-147 info:eu-repo/grantAgreement/ES/DGA/E17-20R info:eu-repo/grantAgreement/ES/DGA-FEDER/Construyendo Europa desde Aragón info:eu-repo/grantAgreement/ES/MICIU-FEDER/PGC2018-094749-B-I00 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 3.876 2020 CHEMISTRY, ORGANIC 13 / 57 = 0.228 2020 Q1 T1 CHEMISTRY, INORGANIC & NUCLEAR 11 / 45 = 0.244 2020 Q1 T1 1.231 2020 Inorganic Chemistry 2020 Q1 Physical and Theoretical Chemistry 2020 Q1 Organic Chemistry 2020 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Arnal, L. Universidad de Zaragoza (orcid)0000-0002-0283-9307 Sicilia, V. Universidad de Zaragoza (orcid)0000-0002-0257-0483 Fuertes, S. (orcid)0000-0003-1812-3175 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 39, 20 (2020), 3695-3704 Organometallics Organometallics 0276-7333 785614 http://zaguan.unizar.es/record/107453/files/texto_completo.pdf Postprint 2959599 http://zaguan.unizar.es/record/107453/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:107453 articulos driver 2024-01-22-15:33:26 ARTICLE