000108272 001__ 108272
000108272 005__ 20211115135503.0
000108272 0247_ $$2doi$$a10.1016/j.apcatb.2019.118360
000108272 0248_ $$2sideral$$a115361
000108272 037__ $$aART-2020-115361
000108272 041__ $$aeng
000108272 100__ $$0(orcid)0000-0003-3211-0485$$aJulian, Ignacio
000108272 245__ $$aSupercritical solvothermal synthesis under reducing conditions to increase stability and durability of Mo/ZSM-5 catalysts in methane dehydroaromatization
000108272 260__ $$c2020
000108272 5060_ $$aAccess copy available to the general public$$fUnrestricted
000108272 5203_ $$aNatural gas is currently envisioned as a potential energy and hydrocarbon feedstock in the forthcoming years. To overcome the detrimental flaring of this natural gas and the partial release of its major component, methane, novel and more effective strategies are required. These include the development of new, efficient and seemingly stable catalysts able to rapidly convert methane into valuable feedstocks. We show a novel synthesis method of Mo/ZSM-5 based on a solvothermal synthesis under supercritical conditions and reducing atmosphere (SC-STSE) to improve metal dispersion and enhance catalyst stability and durability during the methane dehydroaromatization (MDA) reaction. In contrast to the conventional impregnation method, SC-STS-E provides a superhigh atom-like metal dispersion at the zeolite pores resulting in the most stable Mo/ZSM-5 catalyst for MDA with the highest long-term hydrocarbon yield (xCH4=11.6% and yC2+ = 8.9%, after 15 h on stream) among the catalysts reported in literature for this reaction.
000108272 536__ $$9info:eu-repo/grantAgreement/EC/H2020/680777/EU/Adaptable Reactors for Resource- and Energy-Efficient Methane Valorisation/ADREM$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 680777-ADREM
000108272 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000108272 590__ $$a19.503$$b2020
000108272 591__ $$aCHEMISTRY, PHYSICAL$$b8 / 162 = 0.049$$c2020$$dQ1$$eT1
000108272 591__ $$aENGINEERING, ENVIRONMENTAL$$b1 / 53 = 0.019$$c2020$$dQ1$$eT1
000108272 591__ $$aENGINEERING, CHEMICAL$$b3 / 143 = 0.021$$c2020$$dQ1$$eT1
000108272 592__ $$a4.671$$b2020
000108272 593__ $$aCatalysis$$c2020$$dQ1
000108272 593__ $$aProcess Chemistry and Technology$$c2020$$dQ1
000108272 593__ $$aEnvironmental Science (miscellaneous)$$c2020$$dQ1
000108272 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000108272 700__ $$aRoedern, Morten B.
000108272 700__ $$0(orcid)0000-0002-4546-4111$$aHueso, Jose L.
000108272 700__ $$0(orcid)0000-0002-2966-9088$$aIrusta, Silvia$$uUniversidad de Zaragoza
000108272 700__ $$aBadend, Ane K.
000108272 700__ $$0(orcid)0000-0002-4758-9380$$aMallada, Reyes$$uUniversidad de Zaragoza
000108272 700__ $$aDavis, Zachary
000108272 700__ $$0(orcid)0000-0002-8701-9745$$aSantamaria, Jesus$$uUniversidad de Zaragoza
000108272 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000108272 7102_ $$15005$$2790$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Tecnologi. Medio Ambiente
000108272 773__ $$g263 (2020), 118360 1-13$$pAppl. catal., B Environ.$$tAPPLIED CATALYSIS B-ENVIRONMENTAL$$x0926-3373
000108272 8564_ $$s2273632$$uhttps://zaguan.unizar.es/record/108272/files/texto_completo.pdf$$yPostprint
000108272 8564_ $$s1163955$$uhttps://zaguan.unizar.es/record/108272/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000108272 909CO $$ooai:zaguan.unizar.es:108272$$particulos$$pdriver
000108272 951__ $$a2021-11-15-08:51:20
000108272 980__ $$aARTICLE