108285 20230519145344.0 doi 10.1016/j.diamond.2020.108169 sideral 121170 ART-2021-121170 eng Chamorro-Posada, P. Experimental and theoretical investigations on a CVD grown thin film of polymeric carbon nitride and its structure 2021 Access copy available to the general public Unrestricted A polymeric carbon nitride thin film has been grown using chemical vapor deposition. The characterization of the material shows that it has the same molecular composition as a formerly synthesized graphitic carbon nitride powder but both substances differ widely in their structural organization. In particular, our analyses reveal a paradoxical character in which the thin film sample exhibits simultaneously a high degree of organization in the stacking of the polymer sheets with strong inter-layer interactions, as expected from the growth technique, and a complete lack of crystallinity. A comprehensive theoretical study based on massive semi-empirical quantum chemistry computations has permitted to explain the properties of the material and to elucidate fundamental issues regarding the structural conformation of graphitic carbon nitride. info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 3.806 2021 MATERIALS SCIENCE, COATINGS & FILMS 7 / 20 = 0.35 2021 Q2 T2 PHYSICS, CONDENSED MATTER 26 / 69 = 0.377 2021 Q2 T2 PHYSICS, APPLIED 55 / 161 = 0.342 2021 Q2 T2 MATERIALS SCIENCE, MULTIDISCIPLINARY 171 / 345 = 0.496 2021 Q2 T2 0.633 2021 Electronic, Optical and Magnetic Materials 2021 Q1 Chemistry (miscellaneous) 2021 Q1 Physics and Astronomy (miscellaneous) 2021 Q1 Mechanical Engineering 2021 Q1 Materials Chemistry 2021 Q1 5.2 2021 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Dante, R.C. Vázquez-Cabo, J. Dante, D.G. Martín-Ramos, P. Universidad de Zaragoza (orcid)0000-0003-2713-2786 Rubiños-López, Ó. Sánchez-Arévalo, F.M. 5011 500 Universidad de Zaragoza Dpto. CC.Agrar.y Medio Natural Area Ingeniería Agroforestal 111, 108169 (2021), [12 pp] DIAM RELAT MAT Diamond and Related Materials 0925-9635 910688 http://zaguan.unizar.es/record/108285/files/texto_completo.pdf Postprint 2532690 http://zaguan.unizar.es/record/108285/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:108285 articulos driver 2023-05-18-13:19:22 ARTICLE