Resumen: Pinacolborane, catecholborane, triethylsilane, triphenylsilane, dimethylphenylsilane, 1, 1, 1, 3, 5, 5, 5-heptamethyltrisiloxane, triethylgermane, triphenylgermane, and triphenylstannane deuterated at the heteroatom position have been catalytically prepared in 50-70% isolated yield, through H/D exchange between the D2 molecule and the respective boranes and hydrides of the group 14 elements, in the presence of the rhodium(I)-monohydride catalyst precursor RhH{¿3-P, O, P-[xant(PiPr2)2]} (xant(PiPr2)2 = 9, 9-dimethyl-4, 5-bis(diisopropylphosphino)xanthene). Idioma: Inglés DOI: 10.1021/acs.joc.0c01967 Año: 2020 Publicado en: JOURNAL OF ORGANIC CHEMISTRY 85, 23 (2020), 15693-15698 ISSN: 0022-3263 Factor impacto JCR: 4.354 (2020) Categ. JCR: CHEMISTRY, ORGANIC rank: 12 / 57 = 0.211 (2020) - Q1 - T1 Factor impacto SCIMAGO: 1.2 - Organic Chemistry (Q1)