Resumen: Improving e-waste separate collection rates is of the utmost importance to achieve the environmental targets set in the Sustainable Development Goals. Therefore, this paper aims to identify the factors influencing the intentions of Spanish households to separate their e-waste for proper disposal. To this end, we carry out an econometric analysis revealing that the preoccupation with environmental issues is an endogenous regressor, so a bivariate model is required to avoid inconsistent results. The analysis shows that environmental concern and the origin of the individuals are relevant factors that influence the e-waste separation decision. Additionally, we observe an interaction between age and city size, so the effect of one of these factors on the probability of separating e-waste depends on the other factor. Another important result is that several socio-economic variables and knowledge of environmental issues only indirectly affect attitudes, by way of environmental concern. In summary, this study offers a useful methodology to policymakers who have to deal with e-waste management, allowing them to identify the priority groups on which should be focused, as well as to design specific measures tailored to their characteristics. Idioma: Inglés DOI: 10.1007/s11356-021-15933-9 Año: 2022 Publicado en: Environmental Science and Pollution Research 29 (2022), 7185–7201 ISSN: 0944-1344 Factor impacto JCR: 5.8 (2022) Categ. JCR: ENVIRONMENTAL SCIENCES rank: 67 / 275 = 0.244 (2022) - Q1 - T1 Factor impacto CITESCORE: 7.9 - Medicine (Q1) - Environmental Science (Q1)