000108373 001__ 108373
000108373 005__ 20211115162711.0
000108373 0247_ $$2doi$$a10.1039/c5qo00137d
000108373 0248_ $$2sideral$$a124853
000108373 037__ $$aART-2015-124853
000108373 041__ $$aeng
000108373 100__ $$aMejuto, Carmen
000108373 245__ $$aRuthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
000108373 260__ $$c2015
000108373 5060_ $$aAccess copy available to the general public$$fUnrestricted
000108373 5203_ $$a1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic [Ru(NNC)(CO3)(PPh3)] complex, or the [Ru(μ-Cl)(NNC)]2(2Cl−) dimer, was obtained. A di-silver complex in which two ligands are monocoordinated to the metal center through the NHC groups was also obtained and characterised. The dimetallic ruthenium complex reacts with alcohols yielding a monohydride species. The preliminary studies on the catalytic activity of the ruthenium dimer indicate that the complex is active in the reduction of ketones and aldehydes under transfer hydrogenation conditions.
000108373 536__ $$9info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-51999-P$$9info:eu-repo/grantAgreement/ES/MINECO/FPDI-2013-16525
000108373 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000108373 590__ $$a4.693$$b2015
000108373 591__ $$aCHEMISTRY, ORGANIC$$b8 / 59 = 0.136$$c2015$$dQ1$$eT1
000108373 592__ $$a2.31$$b2015
000108373 593__ $$aOrganic Chemistry$$c2015$$dQ1
000108373 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000108373 700__ $$aGarcía-Eleno, Marco A.
000108373 700__ $$0(orcid)0000-0002-0154-9682$$aGuisado-Barrios, Gregorio
000108373 700__ $$aSpasyuk, Denis
000108373 700__ $$aGusev, Dmitri
000108373 700__ $$aPeris, Eduardo
000108373 773__ $$g2, 8 (2015), 936 - 941$$pOrganic chemistry frontiers.$$tOrganic Chemistry Frontiers$$x2052-4129
000108373 8564_ $$s1067680$$uhttps://zaguan.unizar.es/record/108373/files/texto_completo.pdf$$yPostprint
000108373 8564_ $$s1559054$$uhttps://zaguan.unizar.es/record/108373/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000108373 909CO $$ooai:zaguan.unizar.es:108373$$particulos$$pdriver
000108373 951__ $$a2021-11-15-12:18:59
000108373 980__ $$aARTICLE