108373 20211115162711.0 doi 10.1039/c5qo00137d sideral 124853 ART-2015-124853 eng Mejuto, Carmen Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties 2015 1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic [Ru(NNC)(CO3)(PPh3)] complex, or the [Ru(μ-Cl)(NNC)]2(2Cl−) dimer, was obtained. A di-silver complex in which two ligands are monocoordinated to the metal center through the NHC groups was also obtained and characterised. The dimetallic ruthenium complex reacts with alcohols yielding a monohydride species. The preliminary studies on the catalytic activity of the ruthenium dimer indicate that the complex is active in the reduction of ketones and aldehydes under transfer hydrogenation conditions. Access copy available to the general public Unrestricted info:eu-repo/grantAgreement/ES/MINECO/CTQ2014-51999-P info:eu-repo/grantAgreement/ES/MINECO/FPDI-2013-16525 info:eu-repo/semantics/openAccess All rights reserved http://www.europeana.eu/rights/rr-f/ 4.693 2015 CHEMISTRY, ORGANIC 8 / 59 = 0.136 2015 Q1 T1 2.31 2015 Organic Chemistry 2015 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion García-Eleno, Marco A. Guisado-Barrios, Gregorio (orcid)0000-0002-0154-9682 Spasyuk, Denis Gusev, Dmitri Peris, Eduardo 2, 8 (2015), 936 - 941 Organic chemistry frontiers. Organic Chemistry Frontiers 2052-4129 1067680 http://zaguan.unizar.es/record/108373/files/texto_completo.pdf Postprint 1559054 http://zaguan.unizar.es/record/108373/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:108373 articulos driver 2021-11-15-12:18:59 ARTICLE