000109060 001__ 109060
000109060 005__ 20230519145438.0
000109060 0247_ $$2doi$$a10.1002/anie.202015483
000109060 0248_ $$2sideral$$a122459
000109060 037__ $$aART-2021-122459
000109060 041__ $$aeng
000109060 100__ $$aJo, D.
000109060 245__ $$aAn Aluminosilicate Zeolite Containing Rings of Tetrahedral Atoms with All Odd Numbers from Five to Eleven
000109060 260__ $$c2021
000109060 5060_ $$aAccess copy available to the general public$$fUnrestricted
000109060 5203_ $$aHerein we report the synthesis, structure solution, and catalytic properties of PST-31, which has an unprecedented framework topology. This high-silica (Si/Al=16) zeolite was synthesized using a pyrazolium-based dication with a tetramethylene linker as an organic structure-directing agent (OSDA) in hydroxide media. The PST-31 structure is built from new building layers containing four-, five-, six-, and seven-membered rings, which are connected by single four-membered rings in the interlayer region to form a two-dimensional pore system. Its channels consist of [4.56.6.9.11] and [5.6.7.9.10.11] cavities and are thus delimited by nine-, ten-, and eleven-membered rings. The OSDA cations in as-synthesized PST-31 were determined to reside without disorder in the large [42.514.64.72.94] cavities composed of smaller [4.56.6.9.11] and [5.6.7.9.10.11] ones, leading to a symmetry coincidence between the OSDA and the surrounding zeolite cavity. The proton form of PST-31 was found to be selective for the cracking of n-hexane to light olefins.
000109060 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/RYC-2018-024561-I$$9info:eu-repo/grantAgreement/ES/DGA/E13-20R
000109060 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000109060 590__ $$a16.823$$b2021
000109060 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b15 / 180 = 0.083$$c2021$$dQ1$$eT1
000109060 594__ $$a23.9$$b2021
000109060 592__ $$a5.126$$b2021
000109060 593__ $$aChemistry (miscellaneous)$$c2021$$dQ1
000109060 593__ $$aCatalysis$$c2021$$dQ1
000109060 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000109060 700__ $$aZhang, Y.
000109060 700__ $$aLee, J.H.
000109060 700__ $$0(orcid)0000-0002-5229-2717$$aMayoral, A.$$uUniversidad de Zaragoza
000109060 700__ $$aShin, J.
000109060 700__ $$aKang, N.Y.
000109060 700__ $$aPark, Y.K.
000109060 700__ $$aHong, S.B.
000109060 7102_ $$12003$$2395$$aUniversidad de Zaragoza$$bDpto. Física Materia Condensa.$$cÁrea Física Materia Condensada
000109060 773__ $$g60, 11 (2021), 5936-5940$$pAngew. Chem. (Int. ed.)$$tANGEWANDTE CHEMIE-INTERNATIONAL EDITION$$x1433-7851
000109060 8564_ $$s745400$$uhttps://zaguan.unizar.es/record/109060/files/texto_completo.pdf$$yPostprint
000109060 8564_ $$s1067531$$uhttps://zaguan.unizar.es/record/109060/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000109060 909CO $$ooai:zaguan.unizar.es:109060$$particulos$$pdriver
000109060 951__ $$a2023-05-18-14:26:55
000109060 980__ $$aARTICLE