000109077 001__ 109077
000109077 005__ 20211216151748.0
000109077 0247_ $$2doi$$a10.1021/acs.inorgchem.0c02205
000109077 0248_ $$2sideral$$a122578
000109077 037__ $$aART-2020-122578
000109077 041__ $$aeng
000109077 100__ $$0(orcid)0000-0003-3615-1938$$aBould, J.
000109077 245__ $$aLigand Lability Driven by Metal-to-Borane Pseudorotation: A Mechanism for Ligand Exchange
000109077 260__ $$c2020
000109077 5060_ $$aAccess copy available to the general public$$fUnrestricted
000109077 5203_ $$aThe discovery of systems that interact with small molecules plays a vital facilitating role in the development of devices that show sensitivity to their surroundings and an ability to quickly relay chemical and physical information. Herein, we report on the reaction of [NiCl2(dppe)] with decaborane that produces in usable yield a new 11-vertex nickelaborane, [7, 7-(dppe)-nido-7-NiB10H12] (1), which shows interesting reactivity and functionality toward carbon monoxide and ethylisonitrile. This contribution describes the synthesis and full structural characterization of 1 and its small-molecule EtNC and CO adducts, 2 and 3, and delineates the dynamic molecular behavior of all of these species in solution. This information sets a foundation from which more advanced work on this and related metallaborane systems can be conceived and provides a more general reference to how NMR spectroscopy, combined with DFT calculations, can be used to analyze the precise locomotion of labile ligands around a metal center held within a borane cluster.
000109077 536__ $$9info:eu-repo/grantAgreement/ES/MCIU/PGC2018-099383-B-I00
000109077 540__ $$9info:eu-repo/semantics/openAccess$$aAll rights reserved$$uhttp://www.europeana.eu/rights/rr-f/
000109077 590__ $$a5.165$$b2020
000109077 591__ $$aCHEMISTRY, INORGANIC & NUCLEAR$$b5 / 45 = 0.111$$c2020$$dQ1$$eT1
000109077 592__ $$a1.348$$b2020
000109077 593__ $$aChemistry (miscellaneous)$$c2020$$dQ1
000109077 593__ $$aPhysical and Theoretical Chemistry$$c2020$$dQ1
000109077 593__ $$aInorganic Chemistry$$c2020$$dQ1
000109077 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000109077 700__ $$aTok, O.
000109077 700__ $$0(orcid)0000-0002-1735-6439$$aPassarelli, V.$$uUniversidad de Zaragoza
000109077 700__ $$aLondesborough, M.G.S.
000109077 700__ $$0(orcid)0000-0003-2299-9428$$aMaciás, R.$$uUniversidad de Zaragoza
000109077 7102_ $$12010$$2760$$aUniversidad de Zaragoza$$bDpto. Química Inorgánica$$cÁrea Química Inorgánica
000109077 773__ $$g59, 24 (2020), 17958-17969$$pInorg. chem.$$tInorganic Chemistry$$x0020-1669
000109077 8564_ $$s712782$$uhttps://zaguan.unizar.es/record/109077/files/texto_completo.pdf$$yPostprint
000109077 8564_ $$s2819459$$uhttps://zaguan.unizar.es/record/109077/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000109077 909CO $$ooai:zaguan.unizar.es:109077$$particulos$$pdriver
000109077 951__ $$a2021-12-16-12:55:52
000109077 980__ $$aARTICLE