000111642 001__ 111642
000111642 005__ 20230519145453.0
000111642 0247_ $$2doi$$a10.1016/j.micromeso.2021.111487
000111642 0248_ $$2sideral$$a126020
000111642 037__ $$aART-2021-126020
000111642 041__ $$aeng
000111642 100__ $$aPérez-Miana, M.$$uUniversidad de Zaragoza
000111642 245__ $$aSolventless synthesis of ZIF-L and ZIF-8 with hydraulic press and high temperature
000111642 260__ $$c2021
000111642 5060_ $$aAccess copy available to the general public$$fUnrestricted
000111642 5203_ $$aIn recent years, alternative methods to conventional synthesis of MOFs (metal-organic frameworks) have emerged due to the problematic use of solvents for both the environment and human health. Here we present the synthesis of ZIFs (zeolitic imidazolate frameworks) at high pressure by means of a hydraulic press provided with a heating mechanism. By the optimization of parameters such as temperature, time and the addition of promotor NH4NO3, a considerable increase in the reaction yield was achieved in products, neither washed nor activated, obtained since the first minute of reaction. Depending on the operation conditions, ZIF-L appeared as competing phase with ZIF-8. Upon transformation of ZIF-L into ZIF-8 in presence of ethanol, a reaction yield of 58.2% was achieved to highly crystalline ZIF-8 with a BET specific surface area of 947 m2/g. This green, fast, versatile and improved method suggests a possible way to future synthesis of other MOFs and the possibility of their industrial implementation.
000111642 536__ $$9info:eu-repo/grantAgreement/ES/DGA-FSE/T43-20R$$9info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/MAT2016-77290-R$$9info:eu-repo/grantAgreement/ES/MINECO-AEI-FEDER/PID2019-104009RB-I00/AEI/10.13039/501100011033
000111642 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000111642 590__ $$a5.876$$b2021
000111642 592__ $$a0.924$$b2021
000111642 594__ $$a8.9$$b2021
000111642 591__ $$aCHEMISTRY, APPLIED$$b15 / 73 = 0.205$$c2021$$dQ1$$eT1
000111642 593__ $$aChemistry (miscellaneous)$$c2021$$dQ1
000111642 591__ $$aMATERIALS SCIENCE, MULTIDISCIPLINARY$$b106 / 345 = 0.307$$c2021$$dQ2$$eT1
000111642 593__ $$aNanoscience and Nanotechnology$$c2021$$dQ1
000111642 591__ $$aCHEMISTRY, PHYSICAL$$b58 / 165 = 0.352$$c2021$$dQ2$$eT2
000111642 593__ $$aMechanics of Materials$$c2021$$dQ1
000111642 591__ $$aNANOSCIENCE & NANOTECHNOLOGY$$b51 / 109 = 0.468$$c2021$$dQ2$$eT2
000111642 593__ $$aCondensed Matter Physics$$c2021$$dQ1
000111642 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000111642 700__ $$aReséndiz-Ordóñez, J.U.
000111642 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000111642 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000111642 773__ $$g328 (2021), 111487 [10 pp.]$$pMicroporous mesoporous mater.$$tMICROPOROUS AND MESOPOROUS MATERIALS$$x1387-1811
000111642 8564_ $$s5917782$$uhttps://zaguan.unizar.es/record/111642/files/texto_completo.pdf$$yVersión publicada
000111642 8564_ $$s2585838$$uhttps://zaguan.unizar.es/record/111642/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000111642 909CO $$ooai:zaguan.unizar.es:111642$$particulos$$pdriver
000111642 951__ $$a2023-05-18-14:48:09
000111642 980__ $$aARTICLE