000112109 001__ 112109
000112109 005__ 20240319080956.0
000112109 0247_ $$2doi$$a10.1016/j.ceramint.2022.01.063
000112109 0248_ $$2sideral$$a128079
000112109 037__ $$aART-2022-128079
000112109 041__ $$aeng
000112109 100__ $$aCobos, M. Á.
000112109 245__ $$aCoexistence of antiferro- and ferrimagnetism in the spinel ZnFe2O4 with an inversion degree d lower than 0.3
000112109 260__ $$c2022
000112109 5060_ $$aAccess copy available to the general public$$fUnrestricted
000112109 5203_ $$aSamples with inversion parameter values (d) ranging from 0.27 to 0.14 while maintaining the crystallite size value have been successfully fabricated from commercially available powders by mechanical grinding and thermal annealing treatments at temperatures ranging between 400 and 600 °C. Detailed characterization studies of these samples using X-ray, neutron diffraction and magnetic measurements have confirmed for the first time the simultaneous coexistence at 2 K of short range antiferromagnetic and ferrimagnetic ordering for a wide range of the inversion parameter. The magnetic phase diagram obtained is different from the one previously reported, which shows at 2 K the coexistence of long range antiferromagnetic order and short range order for values of inversion parameters less than 0.1 and the presence of a ferrimagnetic order only for values of d > 0.2. At room temperature, the Rietveld analysis of NPD patterns and the magnetization curves showed a paramagnetic behavior in the samples with d = 0.1. For the samples with higher cationic inversion, typical hysteresis curves of ferrimagnetic materials were observed and the saturation magnetization values obtained agree quite well with the net magnetic moment obtained from the Rietveld refinement of the neutron diffraction patterns. © 2022
000112109 536__ $$9info:eu-repo/grantAgreement/ES/MICINN/PID2019-109334RB$$9info:eu-repo/grantAgreement/ES/MICINN/RTI2018-095856-B-C21$$9info:eu-repo/grantAgreement/ES/MINECO/PID2019-109334RB$$9info:eu-repo/grantAgreement/ES/MINECO/RTI2018-095856-B-C21
000112109 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000112109 590__ $$a5.2$$b2022
000112109 592__ $$a0.918$$b2022
000112109 591__ $$aMATERIALS SCIENCE, CERAMICS$$b3 / 29 = 0.103$$c2022$$dQ1$$eT1
000112109 593__ $$aCeramics and Composites$$c2022$$dQ1
000112109 593__ $$aElectronic, Optical and Magnetic Materials$$c2022$$dQ1
000112109 593__ $$aSurfaces, Coatings and Films$$c2022$$dQ1
000112109 593__ $$aMaterials Chemistry$$c2022$$dQ1
000112109 593__ $$aProcess Chemistry and Technology$$c2022$$dQ2
000112109 594__ $$a8.8$$b2022
000112109 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000112109 700__ $$ade la Presa, P.
000112109 700__ $$0(orcid)0000-0001-8224-329X$$aPuente-Orench, I.
000112109 700__ $$aLlorente, I.
000112109 700__ $$aMorales, I.
000112109 700__ $$aGarcía-Escorial, A.
000112109 700__ $$aHernando, A.
000112109 700__ $$aJiménez, J. A.
000112109 773__ $$g48, 9 (2022), 12048-12055$$pCeram. int.$$tCeramics International$$x0272-8842
000112109 8564_ $$s2847076$$uhttps://zaguan.unizar.es/record/112109/files/texto_completo.pdf$$yVersión publicada
000112109 8564_ $$s2417098$$uhttps://zaguan.unizar.es/record/112109/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000112109 909CO $$ooai:zaguan.unizar.es:112109$$particulos$$pdriver
000112109 951__ $$a2024-03-18-13:39:22
000112109 980__ $$aARTICLE