000112119 001__ 112119
000112119 005__ 20240319080957.0
000112119 0247_ $$2doi$$a10.1038/s42004-021-00613-z
000112119 0248_ $$2sideral$$a128089
000112119 037__ $$aART-2022-128089
000112119 041__ $$aeng
000112119 100__ $$aDeacon, A.
000112119 245__ $$aUnderstanding the ZIF-L to ZIF-8 transformation from fundamentals to fully costed kilogram-scale production
000112119 260__ $$c2022
000112119 5060_ $$aAccess copy available to the general public$$fUnrestricted
000112119 5203_ $$aThe metal-organic framework ZIF-8 has demonstrated promise for a wide range of applications, but its synthesis typically involves methodologies that are difficult or expensive to scale up. Here the authors show how the production of nano-ZIF-8 can be conducted at the 1kg scale in an economical manner through the intermediate phase ZIF-L. The production of MOFs at large scale in a sustainable way is key if these materials are to be exploited for their promised widespread application. Much of the published literature has focused on demonstrations of preparation routes using difficult or expensive methodologies to scale. One such MOF is nano-zeolitic imidazolate framework-8 (ZIF-8) - a material of interest for a range of possible applications. Work presented here shows how the synthesis of ZIF-8 can be tracked by a range of methods including X-ray diffraction, thermo gravimetric analysis and inelastic neutron scattering - which offer the prospect of in-line monitoring of the synthesis reaction. Herein we disclose how the production of nano-ZIF-8 can be conducted at scale using the intermediate phase ZIF-L. By understanding the economics and demonstrating the production of 1 kg of nano-ZIF-8 at pilot scale we have shown how this once difficult to make material can be produced to specification in a scalable and cost-efficient fashion.
000112119 536__ $$9info:eu-repo/grantAgreement/EC/H2020/760944/EU/Advanced MEMBranes and membrane assisted procEsses for pre- and post- combustion CO2 captuRe/MEMBER$$9This project has received funding from the European Union’s Horizon 2020 research and innovation program under grant agreement No H2020 760944-MEMBER
000112119 540__ $$9info:eu-repo/semantics/openAccess$$aby$$uhttp://creativecommons.org/licenses/by/3.0/es/
000112119 590__ $$a5.9$$b2022
000112119 592__ $$a1.62$$b2022
000112119 591__ $$aCHEMISTRY, MULTIDISCIPLINARY$$b51 / 178 = 0.287$$c2022$$dQ2$$eT1
000112119 593__ $$aBiochemistry$$c2022$$dQ1
000112119 593__ $$aMaterials Chemistry$$c2022$$dQ1
000112119 593__ $$aEnvironmental Chemistry$$c2022$$dQ1
000112119 593__ $$aChemistry (miscellaneous)$$c2022$$dQ1
000112119 594__ $$a8.9$$b2022
000112119 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/publishedVersion
000112119 700__ $$aBriquet, L.
000112119 700__ $$0(orcid)0000-0001-9595-0831$$aMalankowska, M.
000112119 700__ $$aMassingberd-Mundy, F.
000112119 700__ $$aRudic, S.
000112119 700__ $$aHyde, T. L.
000112119 700__ $$aCavaye, H.
000112119 700__ $$0(orcid)0000-0003-1512-4500$$aCoronas, J.$$uUniversidad de Zaragoza
000112119 700__ $$aPoulston, S.
000112119 700__ $$aJohnson, T.
000112119 7102_ $$15005$$2555$$aUniversidad de Zaragoza$$bDpto. Ing.Quím.Tecnol.Med.Amb.$$cÁrea Ingeniería Química
000112119 773__ $$g5 (2022), 18 [10 pp.]$$tCommunications Chemistry$$x2399-3669
000112119 8564_ $$s2628765$$uhttps://zaguan.unizar.es/record/112119/files/texto_completo.pdf$$yVersión publicada
000112119 8564_ $$s1355371$$uhttps://zaguan.unizar.es/record/112119/files/texto_completo.jpg?subformat=icon$$xicon$$yVersión publicada
000112119 909CO $$ooai:zaguan.unizar.es:112119$$particulos$$pdriver
000112119 951__ $$a2024-03-18-13:47:11
000112119 980__ $$aARTICLE