Cyclopentadienyl iron dicarbonyl styrene chalcogenosulfonates: synthesis and structure of CpFe(CO)(2)SeSO2CH=CHPh

El-Khateeb, Mohammad ; Al-Momani, Alaa ; Garcia-Orduna, Pilar ; Lahoz, Fernando J.

Resumen: In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO)(2)SSO2CH=CHPh (1) and its selenosulfonato analogue CpFe(CO)(2)SeSO2CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (mu-E-x)CpFe(CO)(2)](2) (E = S; x = 2-4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO2CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, H-1-, C-13{H-1}-NMR, UV-Vis spectroscopy and the structure of 2 is determined by X-ray crystallography.

Idioma: Inglés

DOI: 10.1007/s12039-021-02012-2

Año: 2022

Publicado en: JOURNAL OF CHEMICAL SCIENCES 134, 1 (2022), 13 [7 pp]
ISSN: 0974-3626

Factor impacto JCR: 1.7 (2022)

Categ. JCR: CHEMISTRY, MULTIDISCIPLINARY rank: 129 / 178 = 0.725 (2022) - Q3 - T3

Factor impacto CITESCORE: 2.9 - Chemistry (Q3)

Factor impacto SCIMAGO: 0.291 - Chemistry (miscellaneous) (Q3)

Tipo y forma: Artículo (Versión definitiva)