Synthetic natural gas production in a 1 kW reactor using Ni–Ce/Al2O3 and Ru–Ce/Al2O3: Kinetics, catalyst degradation and process design

Bailera, M. (Universidad de Zaragoza) ; Lisbona, P. (Universidad de Zaragoza) ; Peña, B. (Universidad de Zaragoza) ; Alarcón, A. ; Guilera, J. ; Perpiñán, J. (Universidad de Zaragoza) ; Romeo, L. M. (Universidad de Zaragoza)

Resumen: Nickel and ruthenium promoted by ceria were compared as catalyst active phase for the production of synthetic natural gas in a 1 kW fixed-bed reactor (49 cm in length and 3 cm in diameter). Both catalysts were tested in a broad range of conditions: 250–450 °C, 8000–16000 h−1 GHSV, 3.5–5.5H2/CO2 ratio, and atmospheric pressure. The Ni-based catalyst presented higher CO2 conversion and lower reduction of BET area and metal dispersion after utilization. Two kinetic models were elaborated according to the performance of the catalysts in this reactor. The minimum mean squared error between the kinetic model and experiments was 3.0% for the Ru-based catalyst and 1.4% for the Ni-based catalyst. The kinetic model of the Ni-based catalyst was implemented in Aspen Plus to evaluate potential methanation plant designs. The simulation minimized the amount of catalyst required to reach 95 vol% of CH4, within proper technical limits (GHSV 5000 h−1 and temperature 300 °C). The 3-reactor plant was the most adequate configuration. The total catalyst mass was 3.26 kg per kg/h of SNG, the heat removed from the reactors was 10.8 MJ/kgSNG, and the preheating necessity was 4.90 MJ/kgSNG. The electrolysis energy consumption was 86.4 MJ/kgSNG.

Idioma: Inglés

DOI: 10.1016/j.energy.2022.124720

Año: 2022

Publicado en: Energy 256 (2022), 124720 [16 pp.]
ISSN: 0360-5442

Factor impacto JCR: 8.9 (2022)

Categ. JCR: THERMODYNAMICS rank: 3 / 63 = 0.048 (2022) - Q1 - T1
Categ. JCR: ENERGY & FUELS rank: 23 / 119 = 0.193 (2022) - Q1 - T1

Factor impacto CITESCORE: 14.9 - Engineering (Q1) - Energy (Q1) - Environmental Science (Q1)

Factor impacto SCIMAGO: 1.989 - Building and Construction (Q1) - Civil and Structural Engineering (Q1) - Electrical and Electronic Engineering (Q1) - Energy (miscellaneous) (Q1) - Energy Engineering and Power Technology (Q1) - Renewable Energy, Sustainability and the Environment (Q1) - Industrial and Manufacturing Engineering (Q1) - Management, Monitoring, Policy and Law (Q1) - Mechanical Engineering (Q1) - Modeling and Simulation (Q1) - Pollution (Q1) - Fuel Technology (Q1)

Financiación: info:eu-repo/grantAgreement/ES/DGA/T46-17R
Financiación: info:eu-repo/grantAgreement/EC/H2020/887077/EU/Decarbonisation of carbon-intensive industries (Iron and Steel Industries) through Power to gas and Oxy-fuel combustion/DISIPO
Financiación: info:eu-repo/grantAgreement/ES/MINECO-FEDER/ENE2016-76850-R

Tipo y forma: Artículo (PostPrint)

Área (Departamento): Área Máquinas y Motores Térmi. (Dpto. Ingeniería Mecánica)