118228 20220908161755.0 doi 10.1016/j.apenergy.2017.08.048 sideral 101576 ART-2017-101576 eng Gimeno, B. Universidad de Zaragoza (orcid)0000-0002-6992-5656 Influence of SO2 on CO2 storage for CCS technology: Evaluation of CO2/SO2 co-capture 2017 In this work, we determined the influence of SO2 as an impurity in anthropogenic CO2 on carbon capture and storage (CCS) technology. We evaluated the impact on selected injection and storage parameters and the Joule-Thomson coefficient to assess the safety of long-term geological storage of CO2. For this purpose, we obtained new pressure-density-temperature-composition, vapor-liquid-equilibrium, and pressure-speed of sound-temperature-composition experimental data for CO2-rich mixtures containing SO2. To increase the general understanding of the impact of SO2, the compositions cover possible co-capture mixtures, SO2-enriched mixtures, and mixtures similar to industrial emissions. Temperatures and pressures were based on relevant geological storage site values. Our experimental results were used to validate the EOS-CG and PC-SAFT equations of state (EoSs) for CO2 + SO2 under the studied CCS conditions. On the understanding that the chemical reactivity effects due to SO2 have not been considered, we concluded that the presence of SO2 is profitable in most of the studied aspects, especially in the case of shallow reservoirs, and that CO2/SO2 co-capture may be considered as an alternative approach to reduce the costs of CO2 purification. Based on the assessment of the impact of 5 mol% SO2 in the injected fluid in seven saline aquifers, we determined that the reservoirs that would receive the most benefit were Sleipner, Nagaoka and Frio. Access copy available to the general public Unrestricted info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 7.9 2017 ENGINEERING, CHEMICAL 4 / 137 = 0.029 2017 Q1 T1 ENERGY & FUELS 8 / 97 = 0.082 2017 Q1 T1 3.162 2017 Building and Construction 2017 Q1 Civil and Structural Engineering 2017 Q1 Energy (miscellaneous) 2017 Q1 Nuclear Energy and Engineering 2017 Q1 Fuel Technology 2017 Q1 Management, Monitoring, Policy and Law 2017 Q1 Mechanical Engineering 2017 Q1 Energy Engineering and Power Technology 2017 Q1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Artal, M. Universidad de Zaragoza (orcid)0000-0003-1810-9488 Velasco, I. Universidad de Zaragoza (orcid)0000-0001-6607-6858 Blanco, S.T. Universidad de Zaragoza (orcid)0000-0003-2632-2916 Fernández, J. Universidad de Zaragoza (orcid)0000-0001-5256-6055 2012 755 Universidad de Zaragoza Dpto. Química Física Área Química Física 206 (2017), 172-180 Appl. energy Applied Energy 0306-2619 2428867 http://zaguan.unizar.es/record/118228/files/texto_completo.pdf Postprint 462726 http://zaguan.unizar.es/record/118228/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:118228 articulos driver 2022-09-08-14:11:58 ARTICLE