000118229 001__ 118229
000118229 005__ 20220908161755.0
000118229 0247_ $$2doi$$a10.1016/j.ijggc.2013.07.019
000118229 0248_ $$2sideral$$a82849
000118229 037__ $$aART-2013-82849
000118229 041__ $$aeng
000118229 100__ $$aRivas, C.
000118229 245__ $$aInfluence of methane and carbon monoxide in the volumetric behaviour of the anthropogenic CO2: Experimental data and modelling in the critical region
000118229 260__ $$c2013
000118229 5060_ $$aAccess copy available to the general public$$fUnrestricted
000118229 5203_ $$aDensity measurements of the systems CO 2 + CH 4 at T = 304.21 K and CO 2 + CO at T = 304.21 and 308.15 K were carried out at pressures and compositions of interest in the process of transport and storage of
CO 2 (CCS technology): P = 0.1 to 20 MPa, and xCO 2 ≥0.97. From the experimental P––T –xCO 2 data, we have studied the dependence of the isothermal compressibility, the excess molar volume, and the par-
tial molar volume of the solute with composition, pressure and temperature within the critical region. We have modelled the volumetric behaviour of these systems with Peng–Robinson, PC-SAFT and GERG
Equations of State, thus validating these equations under the conditions considered. Furthermore, we have confirmed the weakly attractive behaviour of these systems by performing a study of the interac-
tions between solvent molecules, CO 2 , and those of the solute, CO or CH 4 , using the Krichevskii Function concept and the Kirkwood–Buff Theory. Finally, we have quantified the influence of small amounts of
CH 4 and CO in the transport of anthropogenic CO 2 through several normalized parameters, related to the design and operation of the fluid transport process.
000118229 540__ $$9info:eu-repo/semantics/openAccess$$aby-nc-nd$$uhttp://creativecommons.org/licenses/by-nc-nd/3.0/es/
000118229 590__ $$a3.821$$b2013
000118229 591__ $$aENGINEERING, ENVIRONMENTAL$$b8 / 46 = 0.174$$c2013$$dQ1$$eT1
000118229 591__ $$aENERGY & FUELS$$b16 / 83 = 0.193$$c2013$$dQ1$$eT1
000118229 655_4 $$ainfo:eu-repo/semantics/article$$vinfo:eu-repo/semantics/acceptedVersion
000118229 700__ $$aBlanco, S. T.
000118229 700__ $$aFernández, J.
000118229 700__ $$aArtal, M.
000118229 700__ $$aVelasco, I.
000118229 773__ $$g18 (2013), 264-276$$pInternational Journal of Greenhouse Gas Control$$tInternational Journal of Greenhouse Gas Control$$x1750-5836
000118229 8564_ $$s1274890$$uhttps://zaguan.unizar.es/record/118229/files/texto_completo.pdf$$yPostprint
000118229 8564_ $$s1332331$$uhttps://zaguan.unizar.es/record/118229/files/texto_completo.jpg?subformat=icon$$xicon$$yPostprint
000118229 909CO $$ooai:zaguan.unizar.es:118229$$particulos$$pdriver
000118229 951__ $$a2022-09-08-14:12:08
000118229 980__ $$aARTICLE