118229 20220908161755.0 doi 10.1016/j.ijggc.2013.07.019 sideral 82849 ART-2013-82849 eng Rivas, C. Influence of methane and carbon monoxide in the volumetric behaviour of the anthropogenic CO2: Experimental data and modelling in the critical region 2013 Density measurements of the systems CO 2 + CH 4 at T = 304.21 K and CO 2 + CO at T = 304.21 and 308.15 K were carried out at pressures and compositions of interest in the process of transport and storage of CO 2 (CCS technology): P = 0.1 to 20 MPa, and xCO 2 ≥0.97. From the experimental P––T –xCO 2 data, we have studied the dependence of the isothermal compressibility, the excess molar volume, and the par- tial molar volume of the solute with composition, pressure and temperature within the critical region. We have modelled the volumetric behaviour of these systems with Peng–Robinson, PC-SAFT and GERG Equations of State, thus validating these equations under the conditions considered. Furthermore, we have confirmed the weakly attractive behaviour of these systems by performing a study of the interac- tions between solvent molecules, CO 2 , and those of the solute, CO or CH 4 , using the Krichevskii Function concept and the Kirkwood–Buff Theory. Finally, we have quantified the influence of small amounts of CH 4 and CO in the transport of anthropogenic CO 2 through several normalized parameters, related to the design and operation of the fluid transport process. Access copy available to the general public Unrestricted info:eu-repo/semantics/openAccess by-nc-nd http://creativecommons.org/licenses/by-nc-nd/3.0/es/ 3.821 2013 ENGINEERING, ENVIRONMENTAL 8 / 46 = 0.174 2013 Q1 T1 ENERGY & FUELS 16 / 83 = 0.193 2013 Q1 T1 info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion Blanco, S. T. Fernández, J. Artal, M. Velasco, I. 18 (2013), 264-276 International Journal of Greenhouse Gas Control International Journal of Greenhouse Gas Control 1750-5836 1274890 http://zaguan.unizar.es/record/118229/files/texto_completo.pdf Postprint 1332331 http://zaguan.unizar.es/record/118229/files/texto_completo.jpg?subformat=icon icon Postprint oai:zaguan.unizar.es:118229 articulos driver 2022-09-08-14:12:08 ARTICLE