118955 20240319081010.0 doi 10.1021/acs.inorgchem.2c01902 sideral 130092 ART-2022-130092 eng Carmona, M. Activation of H-H, HO-H, C(sp2)-H, C(sp3)-H, and RO-H bonds by transition-metal frustrated lewis pairs based onon M/N (M = Rh, Ir) couples 2022 Access copy available to the general public Unrestricted Reaction of the dimers (Cp*MCl)2(µ-Cl)2] (Cp* = 5-C5Me5) with Ph2PCH2CH2NC(NH(p-Tolyl))2 (H2L) in the presence of NaSbF6 affords the chlorido complexes Cp*MCl(¿2N, P-H2L)]SbF6] (M = Rh, 1; Ir, 2). Upon treatment with aqueous NaOH, solutions of 1 and 2 yield the corresponding complexes Cp*M(¿3N, N', P-HL)]SbF6] (M = Rh, 3; Ir, 4) in which the ligand HL presents a fac ¿3N, N', P coordination mode. Treatment of THF solutions of complexes 3 and 4 with hydrogen gas, at room temperature, results in the formation of the metal hydrido-complexes Cp*MH(¿2N, P-H2L)]SbF6] (M = Rh, 5; Ir, 6) in which the N(p-Tolyl) group has been protonated. Complexes 3 and 4 react with deuterated water in a reversible fashion resulting in the gradual deuteration of the Cp* group. Heating at 383 K THF/H2O solutions of the complexes 3 and 4 affords the orthometalated complexes Cp*M(¿3C, N, P-H2L-H)]SbF6] M = Rh, 7; Ir, 8, H2L-H = Ph2PCH2CH2NC(NH(p-Tolyl))(NH(4-C6H3Me))], respectively. At 333 K, complexes 3 and 4 react in THF with methanol, primary alcohols, or 2-propanol giving the metal-hydrido complexes 5 and 6, respectively. The reaction involves the acceptorless dehydrogenation of the alcohols at a relatively low temperature, without the assistance of an external base. The new complexes have been characterized by the usual analytical and spectroscopic methods including the X-ray diffraction determination of the crystal structures of complexes 1-5, 7, and 8. Notably, the chlorido complexes 1 and 2 crystallize both as enantiopure conglomerates and as racemates. Reaction mechanisms are proposed based on stoichiometric reactions, nuclear magnetic resonance studies, and X-ray crystallography as well as density functional theory calculations. © 2022 The Authors. Published by American Chemical Society. info:eu-repo/grantAgreement/ES/DGA/E05-20R info:eu-repo/grantAgreement/ES/MCIU/RED2018-102574-T info:eu-repo/grantAgreement/ES/MICINN/CTQ2018-095561-BI00 info:eu-repo/semantics/openAccess by http://creativecommons.org/licenses/by/3.0/es/ 4.6 2022 CHEMISTRY, INORGANIC & NUCLEAR 5 / 42 = 0.119 2022 Q1 T1 0.997 2022 Chemistry (miscellaneous) 2022 Q1 Physical and Theoretical Chemistry 2022 Q1 Inorganic Chemistry 2022 Q1 8.0 2022 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Pérez, R. Ferrer, J. Universidad de Zaragoza (orcid)0000-0003-4568-2204 Rodríguez, R. (orcid)0000-0002-8845-0174 Passarelli, V. (orcid)0000-0002-1735-6439 Lahoz, F. J. (orcid)0000-0001-8054-2237 García-Orduña, P. (orcid)0000-0002-7063-1292 Carmona, D. (orcid)0000-0003-4196-5856 2010 760 Universidad de Zaragoza Dpto. Química Inorgánica Área Química Inorgánica 61, 33 (2022), 13149 - 13164 Inorg. chem. Inorganic Chemistry 0020-1669 5581429 http://zaguan.unizar.es/record/118955/files/texto_completo.pdf Versión publicada 3006427 http://zaguan.unizar.es/record/118955/files/texto_completo.jpg?subformat=icon icon Versión publicada oai:zaguan.unizar.es:118955 articulos driver 2024-03-18-15:04:35 ARTICLE